Pyridyl-1,2,4-triazole diphenyl boron complexes as efficient tuneable blue emitters

Peter Dijkstra; Davide Angelone; Elena Talnishnikh; Heinrich J. Wörtche; Edwin Otten; Wesley R. Browne

doi:10.1039/c4dt01393j

Pyridyl-1,2,4-triazole diphenyl boron complexes as efficient tuneable blue emitters

Peter Dijkstra, Davide Angelone, Elena Talnishnikh, Heinrich J. Wörtche, Edwin Otten, Wesley R. Browne^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › Academic › peer-review

11 Citations (Scopus)

Abstract

The detection of nuclear radiation necessitates the availability of new generations of tunable blue emitting fluorophores with high emission quantum yields. Here we show that pyridyl-1,2,4-triazole based diphenyl boron complexes can provide highly tuneable emission through facile modification of the C5 position of the 1,2,4-triazolato ring. The series of complexes prepared show a wide range of emission from near-UV to green, enabling fine control over the spectral overlap with detectors used in scintillator technology.

Original language	English
Pages (from-to)	17740-17745
Number of pages	6
Journal	Dalton Transactions
Volume	43
Issue number	47
DOIs	https://doi.org/10.1039/c4dt01393j
Publication status	Published - 2014

Keywords

PHOTOPHYSICAL PROPERTIES
BODIPY DYES
SCINTILLATOR
CHEMISTRY
LIGANDS
OLEDS
HOMO

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Pyridyl-1,2,4-triazole diphenyl boron complexes as efficient tuneable blue
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CCDC 1001413: Experimental Crystal Structure Determination
Dijkstra, P. (Contributor), Angelone, D. (Contributor), Talnishnikh, E. (Contributor), Wörtche, H. J. (Contributor), Otten, E. (Contributor) & Browne, W. R. (Contributor), University of Groningen, 6-May-2014
DOI: 10.5517/cc12m1nd
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title = "Pyridyl-1,2,4-triazole diphenyl boron complexes as efficient tuneable blue emitters",

abstract = "The detection of nuclear radiation necessitates the availability of new generations of tunable blue emitting fluorophores with high emission quantum yields. Here we show that pyridyl-1,2,4-triazole based diphenyl boron complexes can provide highly tuneable emission through facile modification of the C5 position of the 1,2,4-triazolato ring. The series of complexes prepared show a wide range of emission from near-UV to green, enabling fine control over the spectral overlap with detectors used in scintillator technology.",

keywords = "PHOTOPHYSICAL PROPERTIES, BODIPY DYES, SCINTILLATOR, CHEMISTRY, LIGANDS, OLEDS, HOMO",

author = "Peter Dijkstra and Davide Angelone and Elena Talnishnikh and W{\"o}rtche, {Heinrich J.} and Edwin Otten and Browne, {Wesley R.}",

year = "2014",

doi = "10.1039/c4dt01393j",

language = "English",

volume = "43",

pages = "17740--17745",

journal = "Dalton Transactions",

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T1 - Pyridyl-1,2,4-triazole diphenyl boron complexes as efficient tuneable blue emitters

AU - Dijkstra, Peter

AU - Angelone, Davide

AU - Talnishnikh, Elena

AU - Wörtche, Heinrich J.

AU - Otten, Edwin

AU - Browne, Wesley R.

PY - 2014

Y1 - 2014

N2 - The detection of nuclear radiation necessitates the availability of new generations of tunable blue emitting fluorophores with high emission quantum yields. Here we show that pyridyl-1,2,4-triazole based diphenyl boron complexes can provide highly tuneable emission through facile modification of the C5 position of the 1,2,4-triazolato ring. The series of complexes prepared show a wide range of emission from near-UV to green, enabling fine control over the spectral overlap with detectors used in scintillator technology.

AB - The detection of nuclear radiation necessitates the availability of new generations of tunable blue emitting fluorophores with high emission quantum yields. Here we show that pyridyl-1,2,4-triazole based diphenyl boron complexes can provide highly tuneable emission through facile modification of the C5 position of the 1,2,4-triazolato ring. The series of complexes prepared show a wide range of emission from near-UV to green, enabling fine control over the spectral overlap with detectors used in scintillator technology.

KW - PHOTOPHYSICAL PROPERTIES

KW - BODIPY DYES

KW - SCINTILLATOR

KW - CHEMISTRY

KW - LIGANDS

KW - OLEDS

KW - HOMO

U2 - 10.1039/c4dt01393j

DO - 10.1039/c4dt01393j

M3 - Article

SN - 1477-9226

VL - 43

SP - 17740

EP - 17745

JO - Dalton Transactions

JF - Dalton Transactions

IS - 47

ER -

Pyridyl-1,2,4-triazole diphenyl boron complexes as efficient tuneable blue emitters

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CCDC 1001413: Experimental Crystal Structure Determination

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