Pyridyl-1,2,4-triazole diphenyl boron complexes as efficient tuneable blue emitters

Peter Dijkstra; Davide Angelone; Elena Talnishnikh; Heinrich J. Wörtche; Edwin Otten; Wesley R. Browne

doi:10.1039/c4dt01393j

Pyridyl-1,2,4-triazole diphenyl boron complexes as efficient tuneable blue emitters

Peter Dijkstra, Davide Angelone, Elena Talnishnikh, Heinrich J. Wörtche, Edwin Otten, Wesley R. Browne^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › Academic › peer-review

8 Citations (Scopus)

Abstract

The detection of nuclear radiation necessitates the availability of new generations of tunable blue emitting fluorophores with high emission quantum yields. Here we show that pyridyl-1,2,4-triazole based diphenyl boron complexes can provide highly tuneable emission through facile modification of the C5 position of the 1,2,4-triazolato ring. The series of complexes prepared show a wide range of emission from near-UV to green, enabling fine control over the spectral overlap with detectors used in scintillator technology.

Original language	English
Pages (from-to)	17740-17745
Number of pages	6
Journal	Dalton Transactions
Volume	43
Issue number	47
DOIs	https://doi.org/10.1039/c4dt01393j
Publication status	Published - 2014

Keywords

PHOTOPHYSICAL PROPERTIES
BODIPY DYES
SCINTILLATOR
CHEMISTRY
LIGANDS
OLEDS
HOMO

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Pyridyl-1,2,4-triazole diphenyl boron complexes as efficient tuneable blue
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CCDC 1001413: Experimental Crystal Structure Determination
Dijkstra, P. (Contributor), Angelone, D. (Contributor), Talnishnikh, E. (Contributor), Wörtche, H. J. (Contributor), Otten, E. (Contributor) & Browne, W. (Contributor), University of Groningen, 6-May-2014
DOI: 10.5517/cc12m1nd
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title = "Pyridyl-1,2,4-triazole diphenyl boron complexes as efficient tuneable blue emitters",

abstract = "The detection of nuclear radiation necessitates the availability of new generations of tunable blue emitting fluorophores with high emission quantum yields. Here we show that pyridyl-1,2,4-triazole based diphenyl boron complexes can provide highly tuneable emission through facile modification of the C5 position of the 1,2,4-triazolato ring. The series of complexes prepared show a wide range of emission from near-UV to green, enabling fine control over the spectral overlap with detectors used in scintillator technology.",

keywords = "PHOTOPHYSICAL PROPERTIES, BODIPY DYES, SCINTILLATOR, CHEMISTRY, LIGANDS, OLEDS, HOMO",

author = "Peter Dijkstra and Davide Angelone and Elena Talnishnikh and W{\"o}rtche, {Heinrich J.} and Edwin Otten and Browne, {Wesley R.}",

year = "2014",

doi = "10.1039/c4dt01393j",

language = "English",

volume = "43",

pages = "17740--17745",

journal = "Dalton Transactions",

issn = "1477-9226",

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T1 - Pyridyl-1,2,4-triazole diphenyl boron complexes as efficient tuneable blue emitters

AU - Dijkstra, Peter

AU - Angelone, Davide

AU - Talnishnikh, Elena

AU - Wörtche, Heinrich J.

AU - Otten, Edwin

AU - Browne, Wesley R.

PY - 2014

Y1 - 2014

N2 - The detection of nuclear radiation necessitates the availability of new generations of tunable blue emitting fluorophores with high emission quantum yields. Here we show that pyridyl-1,2,4-triazole based diphenyl boron complexes can provide highly tuneable emission through facile modification of the C5 position of the 1,2,4-triazolato ring. The series of complexes prepared show a wide range of emission from near-UV to green, enabling fine control over the spectral overlap with detectors used in scintillator technology.

AB - The detection of nuclear radiation necessitates the availability of new generations of tunable blue emitting fluorophores with high emission quantum yields. Here we show that pyridyl-1,2,4-triazole based diphenyl boron complexes can provide highly tuneable emission through facile modification of the C5 position of the 1,2,4-triazolato ring. The series of complexes prepared show a wide range of emission from near-UV to green, enabling fine control over the spectral overlap with detectors used in scintillator technology.

KW - PHOTOPHYSICAL PROPERTIES

KW - BODIPY DYES

KW - SCINTILLATOR

KW - CHEMISTRY

KW - LIGANDS

KW - OLEDS

KW - HOMO

U2 - 10.1039/c4dt01393j

DO - 10.1039/c4dt01393j

M3 - Article

SN - 1477-9226

VL - 43

SP - 17740

EP - 17745

JO - Dalton Transactions

JF - Dalton Transactions

IS - 47

ER -

Pyridyl-1,2,4-triazole diphenyl boron complexes as efficient tuneable blue emitters

Abstract

Keywords

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CCDC 1001413: Experimental Crystal Structure Determination

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