TY - THES
T1 - Quadricyclanen en 3-Oxaquadricyclanen. Overgangsmetaal gekatalyseerde reakties en dynamische processen.
AU - Nusse, Bernard Jozeph
N1 - date_submitted:2008
Rights: University of Groningen
PY - 1978
Y1 - 1978
N2 - In the first part of this thesis are presented the results of a mechanistic study of transition metal- and acid-catalyzed isomerizations of quadricyclanes and 3-oxaquadricyclanes. The second part deals with dynamic processes undergone by [8] (2,4)-1,5-dicarbomethoxy-3-oxaquadricyclane, [8] (1,4)-7-oxanorbornadiene and di-[8] (1,4)-7-oxanorbornadienerhodium chloride. It is shown that substitution at C3 in quadricyclanes has no substantial effect on either the rates or nature of the products of the Rh2 (NOR)2CL2-catalyzed valence-isomerization of these compounds. ...
Zie: Summary
Zie: Summary of
AB - In the first part of this thesis are presented the results of a mechanistic study of transition metal- and acid-catalyzed isomerizations of quadricyclanes and 3-oxaquadricyclanes. The second part deals with dynamic processes undergone by [8] (2,4)-1,5-dicarbomethoxy-3-oxaquadricyclane, [8] (1,4)-7-oxanorbornadiene and di-[8] (1,4)-7-oxanorbornadienerhodium chloride. It is shown that substitution at C3 in quadricyclanes has no substantial effect on either the rates or nature of the products of the Rh2 (NOR)2CL2-catalyzed valence-isomerization of these compounds. ...
Zie: Summary
Zie: Summary of
M3 - Thesis fully internal (DIV)
PB - VRB Offsetdrukkerij bv Groningen
ER -