Rate-determining electron-transfer reactions in highly aqueous alcohol-water mixtures. A quantitative analysis of solvent effects on the oxidation of 4-methoxyphenylacetate by potassium 12-tungstocobaltate(III)

M. Bietti; E. Baciocchi; J.B.F.N. Engberts

doi:10.1039/cc9960001307

Rate-determining electron-transfer reactions in highly aqueous alcohol-water mixtures. A quantitative analysis of solvent effects on the oxidation of 4-methoxyphenylacetate by potassium 12-tungstocobaltate(III)

M. Bietti, E. Baciocchi, J.B.F.N. Engberts

Research output: Contribution to journal › Article › Academic › peer-review

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Abstract

Kinetic solvent effects on the rate-determining outer-sphere electron-transfer reaction between 4-methoxy-phenylacetate and potassium 12-tungstocobaltate(III) in highly aqueous alcohol-water mixtures are quantitatively analysed in terms of pairwise Gibbs energy parameters for interaction of the initial and transition state with the cosolvent.

Original language	English
Pages (from-to)	1307-1308
Number of pages	2
Journal	Chemical Communications
Volume	11
Issue number	11
DOIs	https://doi.org/10.1039/cc9960001307
Publication status	Published - 7-Jun-1996

Keywords

HYDROLYSIS
COUPLE
UREA

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title = "Rate-determining electron-transfer reactions in highly aqueous alcohol-water mixtures. A quantitative analysis of solvent effects on the oxidation of 4-methoxyphenylacetate by potassium 12-tungstocobaltate(III)",

abstract = "Kinetic solvent effects on the rate-determining outer-sphere electron-transfer reaction between 4-methoxy-phenylacetate and potassium 12-tungstocobaltate(III) in highly aqueous alcohol-water mixtures are quantitatively analysed in terms of pairwise Gibbs energy parameters for interaction of the initial and transition state with the cosolvent.",

keywords = "HYDROLYSIS, COUPLE, UREA",

author = "M. Bietti and E. Baciocchi and J.B.F.N. Engberts",

note = "Journal UN 7 R347 HEM COMMUN",

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doi = "10.1039/cc9960001307",

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volume = "11",

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Rate-determining electron-transfer reactions in highly aqueous alcohol-water mixtures. A quantitative analysis of solvent effects on the oxidation of 4-methoxyphenylacetate by potassium 12-tungstocobaltate(III). / Bietti, M.; Baciocchi, E.; Engberts, J.B.F.N.
In: Chemical Communications, Vol. 11, No. 11, 07.06.1996, p. 1307-1308.

Research output: Contribution to journal › Article › Academic › peer-review

TY - JOUR

T1 - Rate-determining electron-transfer reactions in highly aqueous alcohol-water mixtures. A quantitative analysis of solvent effects on the oxidation of 4-methoxyphenylacetate by potassium 12-tungstocobaltate(III)

AU - Bietti, M.

AU - Baciocchi, E.

AU - Engberts, J.B.F.N.

N1 - Journal UN 7 R347 HEM COMMUN

PY - 1996/6/7

Y1 - 1996/6/7

N2 - Kinetic solvent effects on the rate-determining outer-sphere electron-transfer reaction between 4-methoxy-phenylacetate and potassium 12-tungstocobaltate(III) in highly aqueous alcohol-water mixtures are quantitatively analysed in terms of pairwise Gibbs energy parameters for interaction of the initial and transition state with the cosolvent.

AB - Kinetic solvent effects on the rate-determining outer-sphere electron-transfer reaction between 4-methoxy-phenylacetate and potassium 12-tungstocobaltate(III) in highly aqueous alcohol-water mixtures are quantitatively analysed in terms of pairwise Gibbs energy parameters for interaction of the initial and transition state with the cosolvent.

KW - HYDROLYSIS

KW - COUPLE

KW - UREA

U2 - 10.1039/cc9960001307

DO - 10.1039/cc9960001307

M3 - Article

SN - 1359-7345

VL - 11

SP - 1307

EP - 1308

JO - Chemical Communications

JF - Chemical Communications

IS - 11

ER -