TY - JOUR
T1 - Recycling behavior of thermoreversibly Diels-Alder crosslinked EPM
AU - Zdvizhkov, Alexander T.
AU - Van Duin, Martin
AU - Picchioni, Francesco
N1 - Publisher Copyright:
© 2021 Rubber Division of the American Chemical Society. All rights reserved.
PY - 2021/4
Y1 - 2021/4
N2 - The recyclability of thermoreversibly Diels-Alder (DA) crosslinked EPM has been studied. The retro DA reaction dominates over the dehydration-aromatization process of theDAadduct. Moreover, a negative influence of air occurred as a result of a crosslinking in air flow. Nevertheless, rubber compounds prepared from EPM-g-furan and carbon black can be recycled several times without losing mechanical strength, a feature attributed to a strong antioxidant effect of the carbon black.
AB - The recyclability of thermoreversibly Diels-Alder (DA) crosslinked EPM has been studied. The retro DA reaction dominates over the dehydration-aromatization process of theDAadduct. Moreover, a negative influence of air occurred as a result of a crosslinking in air flow. Nevertheless, rubber compounds prepared from EPM-g-furan and carbon black can be recycled several times without losing mechanical strength, a feature attributed to a strong antioxidant effect of the carbon black.
UR - http://www.scopus.com/inward/record.url?scp=85109301311&partnerID=8YFLogxK
U2 - 10.5254/rct.21.79971
DO - 10.5254/rct.21.79971
M3 - Article
AN - SCOPUS:85109301311
VL - 94
SP - 288
EP - 297
JO - Rubber chemistry and technology
JF - Rubber chemistry and technology
SN - 0035-9475
IS - 2
ER -