Relativistic coupled-cluster studies of ionization potentials, lifetimes, and polarizabilities in singly ionized calcium

B. K. Sahoo*, B. P. Das, D. Mukherjee

*Corresponding author for this work

    Research output: Contribution to journalArticleAcademicpeer-review

    42 Citations (Scopus)

    Abstract

    Using the relativistic coupled-cluster method, we have calculated ionization potentials, electric dipole transition amplitudes, and dipole polarizabilities of many low-lying states of Ca(+). Contributions from the Breit interaction are given explicitly for these properties. Polarizabilities of the ground and the first excited d states are determined by evaluating the wave functions that are perturbed to first order by the electric dipole operator and the black-body radiation shifts are estimated from these results. We also report the results of branching ratios and lifetimes of the first excited p states using both the calculated and experimental wavelengths and compare them with their measured values.

    Original languageEnglish
    Article number052511
    Number of pages9
    JournalPhysical Review A
    Volume79
    Issue number5
    DOIs
    Publication statusPublished - May-2009

    Keywords

    • calcium
    • coupled cluster calculations
    • excited states
    • ground states
    • ionisation potential
    • polarisability
    • positive ions
    • radiative lifetimes
    • relativistic corrections
    • wave functions
    • CA-II
    • 4P LEVELS
    • IONS
    • PRECISION
    • DIPOLE
    • ATOMS
    • MG+
    • FREQUENCY
    • MAGNESIUM
    • EMISSION

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