Abstract
Using the relativistic coupled-cluster method, we have calculated ionization potentials, electric dipole transition amplitudes, and dipole polarizabilities of many low-lying states of Ca(+). Contributions from the Breit interaction are given explicitly for these properties. Polarizabilities of the ground and the first excited d states are determined by evaluating the wave functions that are perturbed to first order by the electric dipole operator and the black-body radiation shifts are estimated from these results. We also report the results of branching ratios and lifetimes of the first excited p states using both the calculated and experimental wavelengths and compare them with their measured values.
Original language | English |
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Article number | 052511 |
Number of pages | 9 |
Journal | Physical Review A |
Volume | 79 |
Issue number | 5 |
DOIs | |
Publication status | Published - May-2009 |
Keywords
- calcium
- coupled cluster calculations
- excited states
- ground states
- ionisation potential
- polarisability
- positive ions
- radiative lifetimes
- relativistic corrections
- wave functions
- CA-II
- 4P LEVELS
- IONS
- PRECISION
- DIPOLE
- ATOMS
- MG+
- FREQUENCY
- MAGNESIUM
- EMISSION