Revisiting Formal Copper(III) Complexes: Bridging Perspectives with Quasi-d10 Configurations

Isaac F. Leach, Remco W.A. Havenith, Johannes E.M.N. Klein*

*Corresponding author for this work

Research output: Contribution to journalArticleAcademicpeer-review

11 Citations (Scopus)
83 Downloads (Pure)

Abstract

The formal Cu(III) complex [Cu(CF3)4]1− has often served as a paradigmatic example of challenging oxidation state assignment – with many reports proposing conflicting descriptions. Here we report a computational analysis of this compound, employing Energy Decomposition Analysis and Intrinsic Bond Orbital Analysis. We present a quasi-d10 perspective of the metal centre, resulting from ambiguities in d-electron counting. The implications for describing reactions which undergo oxidation state changes, such as the formal reductive elimination from the analogous [Cu(CF3)3(CH2Ph)]1− complex (Paeth et al. J. Am. Chem. Soc. 2019, 141, 3153), are probed. Electron flow analysis finds that the changes in electronic structure may be understood as a quasi-d10 to d10 transition at the metal centre, rendering this process essentially redox neutral. This is reminiscent of a previously studied formal Ni(IV) complex (Steen et al., Angew. Chem. Int. Ed. 2019, 58, 13133–13139), and indicates that our description of electronic structure has implications for the understanding of elementary organometallic reaction steps.

Original languageEnglish
Article numbere202200247
Number of pages8
JournalEuropean Journal of Inorganic Chemistry
Volume2022
Issue number27
DOIs
Publication statusPublished - 27-Sept-2022

Keywords

  • Bonding theory
  • Computational chemistry
  • Oxidation states
  • Population analysis
  • Transition metals

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