Self-assembly of novel supramolecular silver(I) compound based on mixed ligands bipy/TST3- H3TST=2,4,6-tris (4-sulfophenylamino)-1,3,5-triazine

Yunfang Yu, Yongqin Wei, Ria Broer, Kechen Wu*

*Corresponding author for this work

Research output: Contribution to journalArticleAcademicpeer-review

9 Citations (Scopus)
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Abstract

The novel supramolecular silver(I) compound with formula [Ag-6(TST)(2)(bipy)(6)(H2O)(2)](n) center dot 3nH(2)O (1) based on assembly of Ag(I) and mixed ligand bipy/TST3-, bipy = 2,2'-bipyridine, H3TST = 2,4,6-tris(4-sulfophenylamino)-1,3,5-triazine, has been prepared by hydrothermal method. In the solid-state structure of 1, two-dimensional layered polymeric structures extended with subunits [Ag-6(TST)(2)(bipy)(6)(H2O)(2)] interact each other in the form of pi-pi attractions between bipy, forming a three-dimensional supramolecular architecture. Compound 1 represents a Ag-containing polymeric compound possessing room-temperature luminescence. (c) 2007 Elsevier B.V. All rights reserved.

Original languageEnglish
Pages (from-to)1289-1293
Number of pages5
JournalInorganic Chemistry Communications
Volume10
Issue number11
DOIs
Publication statusPublished - Nov-2007

Keywords

  • hydrothermal method
  • supramolecular compound
  • self-assembly
  • luminescence
  • HYDROGEN-BONDED NETWORKS
  • COORDINATION POLYMERS
  • CRYSTAL-STRUCTURES
  • BRIDGING LIGANDS
  • COMPLEXES
  • DESIGN
  • 1,10-PHENANTHROLINE
  • 2,2-BIPYRIDINE
  • LUMINESCENCE
  • SERIES

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