Abstract
The novel supramolecular silver(I) compound with formula [Ag-6(TST)(2)(bipy)(6)(H2O)(2)](n) center dot 3nH(2)O (1) based on assembly of Ag(I) and mixed ligand bipy/TST3-, bipy = 2,2'-bipyridine, H3TST = 2,4,6-tris(4-sulfophenylamino)-1,3,5-triazine, has been prepared by hydrothermal method. In the solid-state structure of 1, two-dimensional layered polymeric structures extended with subunits [Ag-6(TST)(2)(bipy)(6)(H2O)(2)] interact each other in the form of pi-pi attractions between bipy, forming a three-dimensional supramolecular architecture. Compound 1 represents a Ag-containing polymeric compound possessing room-temperature luminescence. (c) 2007 Elsevier B.V. All rights reserved.
Original language | English |
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Pages (from-to) | 1289-1293 |
Number of pages | 5 |
Journal | Inorganic Chemistry Communications |
Volume | 10 |
Issue number | 11 |
DOIs | |
Publication status | Published - Nov-2007 |
Keywords
- hydrothermal method
- supramolecular compound
- self-assembly
- luminescence
- HYDROGEN-BONDED NETWORKS
- COORDINATION POLYMERS
- CRYSTAL-STRUCTURES
- BRIDGING LIGANDS
- COMPLEXES
- DESIGN
- 1,10-PHENANTHROLINE
- 2,2-BIPYRIDINE
- LUMINESCENCE
- SERIES
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Dive into the research topics of 'Self-assembly of novel supramolecular silver(I) compound based on mixed ligands bipy/TST3- H3TST=2,4,6-tris (4-sulfophenylamino)-1,3,5-triazine'. Together they form a unique fingerprint.Datasets
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CCDC 636258: Experimental Crystal Structure Determination
Yu, Y. (Contributor), Wei, Y. (Contributor), Braam, R. (Contributor) & Wu, K. (Contributor), University of Groningen, 8-Feb-2007
DOI: 10.5517/ccpc2gk
Dataset