Self-assembly of novel supramolecular silver(I) compound based on mixed ligands bipy/TST3- H3TST=2,4,6-tris (4-sulfophenylamino)-1,3,5-triazine

Yunfang Yu; Yongqin Wei; Ria Broer; Kechen Wu

doi:10.1016/j.inoche.2007.07.024

Self-assembly of novel supramolecular silver(I) compound based on mixed ligands bipy/TST3- H3TST=2,4,6-tris (4-sulfophenylamino)-1,3,5-triazine

Yunfang Yu, Yongqin Wei, Ria Broer, Kechen Wu^*

^*Corresponding author for this work

Theoretical Chemistry

Research output: Contribution to journal › Article › Academic › peer-review

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Abstract

The novel supramolecular silver(I) compound with formula [Ag-6(TST)(2)(bipy)(6)(H2O)(2)](n) center dot 3nH(2)O (1) based on assembly of Ag(I) and mixed ligand bipy/TST3-, bipy = 2,2'-bipyridine, H3TST = 2,4,6-tris(4-sulfophenylamino)-1,3,5-triazine, has been prepared by hydrothermal method. In the solid-state structure of 1, two-dimensional layered polymeric structures extended with subunits [Ag-6(TST)(2)(bipy)(6)(H2O)(2)] interact each other in the form of pi-pi attractions between bipy, forming a three-dimensional supramolecular architecture. Compound 1 represents a Ag-containing polymeric compound possessing room-temperature luminescence. (c) 2007 Elsevier B.V. All rights reserved.

Original language	English
Pages (from-to)	1289-1293
Number of pages	5
Journal	Inorganic Chemistry Communications
Volume	10
Issue number	11
DOIs	https://doi.org/10.1016/j.inoche.2007.07.024
Publication status	Published - Nov-2007

Keywords

hydrothermal method
supramolecular compound
self-assembly
luminescence
HYDROGEN-BONDED NETWORKS
COORDINATION POLYMERS
CRYSTAL-STRUCTURES
BRIDGING LIGANDS
COMPLEXES
DESIGN
1,10-PHENANTHROLINE
2,2-BIPYRIDINE
LUMINESCENCE
SERIES

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CCDC 636258: Experimental Crystal Structure Determination
Yu, Y. (Contributor), Wei, Y. (Contributor), Braam, R. (Contributor) & Wu, K. (Contributor), University of Groningen, 8-Feb-2007
DOI: 10.5517/ccpc2gk
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@article{56150032761a477a9a610819a8405227,

title = "Self-assembly of novel supramolecular silver(I) compound based on mixed ligands bipy/TST3- H3TST=2,4,6-tris (4-sulfophenylamino)-1,3,5-triazine",

abstract = "The novel supramolecular silver(I) compound with formula [Ag-6(TST)(2)(bipy)(6)(H2O)(2)](n) center dot 3nH(2)O (1) based on assembly of Ag(I) and mixed ligand bipy/TST3-, bipy = 2,2'-bipyridine, H3TST = 2,4,6-tris(4-sulfophenylamino)-1,3,5-triazine, has been prepared by hydrothermal method. In the solid-state structure of 1, two-dimensional layered polymeric structures extended with subunits [Ag-6(TST)(2)(bipy)(6)(H2O)(2)] interact each other in the form of pi-pi attractions between bipy, forming a three-dimensional supramolecular architecture. Compound 1 represents a Ag-containing polymeric compound possessing room-temperature luminescence. (c) 2007 Elsevier B.V. All rights reserved.",

keywords = "hydrothermal method, supramolecular compound, self-assembly, luminescence, HYDROGEN-BONDED NETWORKS, COORDINATION POLYMERS, CRYSTAL-STRUCTURES, BRIDGING LIGANDS, COMPLEXES, DESIGN, 1,10-PHENANTHROLINE, 2,2-BIPYRIDINE, LUMINESCENCE, SERIES",

author = "Yunfang Yu and Yongqin Wei and Ria Broer and Kechen Wu",

year = "2007",

month = nov,

doi = "10.1016/j.inoche.2007.07.024",

language = "English",

volume = "10",

pages = "1289--1293",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier",

number = "11",

}

TY - JOUR

T1 - Self-assembly of novel supramolecular silver(I) compound based on mixed ligands bipy/TST3- H3TST=2,4,6-tris (4-sulfophenylamino)-1,3,5-triazine

AU - Yu, Yunfang

AU - Wei, Yongqin

AU - Broer, Ria

AU - Wu, Kechen

PY - 2007/11

Y1 - 2007/11

N2 - The novel supramolecular silver(I) compound with formula [Ag-6(TST)(2)(bipy)(6)(H2O)(2)](n) center dot 3nH(2)O (1) based on assembly of Ag(I) and mixed ligand bipy/TST3-, bipy = 2,2'-bipyridine, H3TST = 2,4,6-tris(4-sulfophenylamino)-1,3,5-triazine, has been prepared by hydrothermal method. In the solid-state structure of 1, two-dimensional layered polymeric structures extended with subunits [Ag-6(TST)(2)(bipy)(6)(H2O)(2)] interact each other in the form of pi-pi attractions between bipy, forming a three-dimensional supramolecular architecture. Compound 1 represents a Ag-containing polymeric compound possessing room-temperature luminescence. (c) 2007 Elsevier B.V. All rights reserved.

AB - The novel supramolecular silver(I) compound with formula [Ag-6(TST)(2)(bipy)(6)(H2O)(2)](n) center dot 3nH(2)O (1) based on assembly of Ag(I) and mixed ligand bipy/TST3-, bipy = 2,2'-bipyridine, H3TST = 2,4,6-tris(4-sulfophenylamino)-1,3,5-triazine, has been prepared by hydrothermal method. In the solid-state structure of 1, two-dimensional layered polymeric structures extended with subunits [Ag-6(TST)(2)(bipy)(6)(H2O)(2)] interact each other in the form of pi-pi attractions between bipy, forming a three-dimensional supramolecular architecture. Compound 1 represents a Ag-containing polymeric compound possessing room-temperature luminescence. (c) 2007 Elsevier B.V. All rights reserved.

KW - hydrothermal method

KW - supramolecular compound

KW - self-assembly

KW - luminescence

KW - HYDROGEN-BONDED NETWORKS

KW - COORDINATION POLYMERS

KW - CRYSTAL-STRUCTURES

KW - BRIDGING LIGANDS

KW - COMPLEXES

KW - DESIGN

KW - 1,10-PHENANTHROLINE

KW - 2,2-BIPYRIDINE

KW - LUMINESCENCE

KW - SERIES

U2 - 10.1016/j.inoche.2007.07.024

DO - 10.1016/j.inoche.2007.07.024

M3 - Article

SN - 1387-7003

VL - 10

SP - 1289

EP - 1293

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 11

ER -

Self-assembly of novel supramolecular silver(I) compound based on mixed ligands bipy/TST3- H3TST=2,4,6-tris (4-sulfophenylamino)-1,3,5-triazine

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CCDC 636258: Experimental Crystal Structure Determination

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