Sequence-complementarity dependent co-assembly of phosphodiester-linked aromatic donor-acceptor trimers

Nadeema Appukutti; Alex H de Vries; Prashant G Gudeangadi; Bini R Claringbold; Michelle D Garrett; Michael R Reithofer; Christopher J Serpell

doi:10.1039/d2cc00239f

Sequence-complementarity dependent co-assembly of phosphodiester-linked aromatic donor-acceptor trimers

Nadeema Appukutti, Alex H de Vries, Prashant G Gudeangadi, Bini R Claringbold, Michelle D Garrett, Michael R Reithofer, Christopher J Serpell^*

^*Corresponding author for this work

Molecular Dynamics

Research output: Contribution to journal › Article › Academic › peer-review

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Abstract

We have created sequenced phosphoester-linked trimers of aromatic donor/acceptors which participate in charge-transfer interactions. Each sequence displays characteristic self-assembly, and complementary sequences interact with each other to produce new nanostructures and thermochromism. This paves the way towards new functional nanomaterials which make bio-analogous use of sequence to tune structure.

Original language	English
Pages (from-to)	12200-12203
Number of pages	4
Journal	Chemical communications (Cambridge, England)
Volume	58
Issue number	87
Early online date	14-Oct-2022
DOIs	https://doi.org/10.1039/d2cc00239f
Publication status	Published - Nov-2022

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10.1039/d2cc00239fLicence: CC BY

Sequence-complementarity dependent co-assembly of phosphodiester-linked aromatic donor–acceptor trimersProof, 2.44 MBLicence: CC BY

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title = "Sequence-complementarity dependent co-assembly of phosphodiester-linked aromatic donor-acceptor trimers",

abstract = "We have created sequenced phosphoester-linked trimers of aromatic donor/acceptors which participate in charge-transfer interactions. Each sequence displays characteristic self-assembly, and complementary sequences interact with each other to produce new nanostructures and thermochromism. This paves the way towards new functional nanomaterials which make bio-analogous use of sequence to tune structure.",

author = "Nadeema Appukutti and {de Vries}, {Alex H} and Gudeangadi, {Prashant G} and Claringbold, {Bini R} and Garrett, {Michelle D} and Reithofer, {Michael R} and Serpell, {Christopher J}",

year = "2022",

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language = "English",

volume = "58",

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AU - Appukutti, Nadeema

AU - de Vries, Alex H

AU - Gudeangadi, Prashant G

AU - Claringbold, Bini R

AU - Garrett, Michelle D

AU - Reithofer, Michael R

AU - Serpell, Christopher J

PY - 2022/11

Y1 - 2022/11

N2 - We have created sequenced phosphoester-linked trimers of aromatic donor/acceptors which participate in charge-transfer interactions. Each sequence displays characteristic self-assembly, and complementary sequences interact with each other to produce new nanostructures and thermochromism. This paves the way towards new functional nanomaterials which make bio-analogous use of sequence to tune structure.

AB - We have created sequenced phosphoester-linked trimers of aromatic donor/acceptors which participate in charge-transfer interactions. Each sequence displays characteristic self-assembly, and complementary sequences interact with each other to produce new nanostructures and thermochromism. This paves the way towards new functional nanomaterials which make bio-analogous use of sequence to tune structure.

U2 - 10.1039/d2cc00239f

DO - 10.1039/d2cc00239f

M3 - Article

C2 - 36239130

SN - 1359-7345

VL - 58

SP - 12200

EP - 12203

JO - Chemical communications (Cambridge, England)

JF - Chemical communications (Cambridge, England)

IS - 87

ER -