Spin Transition Evidenced by Soft X-ray Absorption Spectroscopy

Christophe Cartier dit Moulin; Petra Rudolf; Anne-Marie Flank; Chien-Te Chen

doi:10.1021/j100194a021

Spin Transition Evidenced by Soft X-ray Absorption Spectroscopy

Christophe Cartier dit Moulin, Petra Rudolf, Anne-Marie Flank, Chien-Te Chen

Zernike Institute for Advanced Materials

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Abstract

Iron L2,3 X-ray absorption spectra have been recorded in order to follow the thermal reversible spin interconversion of the FeII(phen)2(NCS)2 (phen = o-phenanthroline). Important differences are observed which show that this spectroscopy is a fingerprint of the spin state. The evolution of the branching ratio is discussed and found to be consistent with the expected value obtained by multiplet calculations.

Original language	English
Number of pages	3
Journal	The Journal of Physical Chemistry
Volume	96
Issue number	15
DOIs	https://doi.org/10.1021/j100194a021
Publication status	Published - 1992

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Cite this

@article{147513db26fc49fe80798717980bdff5,

title = "Spin Transition Evidenced by Soft X-ray Absorption Spectroscopy",

abstract = "Iron L2,3 X-ray absorption spectra have been recorded in order to follow the thermal reversible spin interconversion of the FeII(phen)2(NCS)2 (phen = o-phenanthroline). Important differences are observed which show that this spectroscopy is a fingerprint of the spin state. The evolution of the branching ratio is discussed and found to be consistent with the expected value obtained by multiplet calculations.",

author = "{Cartier dit Moulin}, Christophe and Petra Rudolf and Anne-Marie Flank and Chien-Te Chen",

note = "Relation: http://www.rug.nl/natuurkunde/ date_submitted:2006 Rights: University of Groningen. Materials Science Centre",

year = "1992",

doi = "10.1021/j100194a021",

language = "English",

volume = "96",

journal = "The Journal of Physical Chemistry",

issn = "0022-3654",

publisher = "AMER CHEMICAL SOC",

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T1 - Spin Transition Evidenced by Soft X-ray Absorption Spectroscopy

AU - Cartier dit Moulin, Christophe

AU - Rudolf, Petra

AU - Flank, Anne-Marie

AU - Chen, Chien-Te

N1 - Relation: http://www.rug.nl/natuurkunde/ date_submitted:2006 Rights: University of Groningen. Materials Science Centre

PY - 1992

Y1 - 1992

N2 - Iron L2,3 X-ray absorption spectra have been recorded in order to follow the thermal reversible spin interconversion of the FeII(phen)2(NCS)2 (phen = o-phenanthroline). Important differences are observed which show that this spectroscopy is a fingerprint of the spin state. The evolution of the branching ratio is discussed and found to be consistent with the expected value obtained by multiplet calculations.

AB - Iron L2,3 X-ray absorption spectra have been recorded in order to follow the thermal reversible spin interconversion of the FeII(phen)2(NCS)2 (phen = o-phenanthroline). Important differences are observed which show that this spectroscopy is a fingerprint of the spin state. The evolution of the branching ratio is discussed and found to be consistent with the expected value obtained by multiplet calculations.

U2 - 10.1021/j100194a021

DO - 10.1021/j100194a021

M3 - Article

VL - 96

JO - The Journal of Physical Chemistry

JF - The Journal of Physical Chemistry

SN - 0022-3654

IS - 15

ER -