Stepwise Ti-Cl, Ti-CH3, and Ti-C6H5 bond dissociation enthalpies in bis(pentamethylcyclopentadienyl)titanium complexes

Alberto R. Dias; Margarida S. Salema; Jose A. Martinho Simões; Johannes W. Pattiasina; Jan H. Teuben

doi:10.1016/0022-328X(88)87013-X

Stepwise Ti-Cl, Ti-CH3, and Ti-C6H5 bond dissociation enthalpies in bis(pentamethylcyclopentadienyl)titanium complexes

Alberto R. Dias, Margarida S. Salema, Jose A. Martinho Simões, Johannes W. Pattiasina, Jan H. Teuben

Stratingh Institute for Chemistry

Research output: Contribution to journal › Article › Academic › peer-review

15 Citations (Scopus)

Abstract

Reaction-solution calorimetric studies involving the complexes Ti[η5-C5(CH3)5]2(CH3)2, Ti[η5-C5(CH3)5]2(CH3), Ti[η5-C5(CH3)5]2(C6H5), Ti[η5-C5(CH3)5]2Cl2, and Ti[η5-C5(CH3)5]2Cl, have enabled derivation of titanium-carbon and titanium-chlorine stepwise bond dissociation enthalpies in these species.

Original language	English
Pages (from-to)	C4-C6
Number of pages	3
Journal	Journal of Organometallic Chemistry
Volume	346
Issue number	1
DOIs	https://doi.org/10.1016/0022-328X(88)87013-X
Publication status	Published - 17-May-1988

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@article{447d93fd80ae4132b9e970cfcce956a2,

title = "Stepwise Ti-Cl, Ti-CH3, and Ti-C6H5 bond dissociation enthalpies in bis(pentamethylcyclopentadienyl)titanium complexes",

abstract = "Reaction-solution calorimetric studies involving the complexes Ti[η5-C5(CH3)5]2(CH3)2, Ti[η5-C5(CH3)5]2(CH3), Ti[η5-C5(CH3)5]2(C6H5), Ti[η5-C5(CH3)5]2Cl2, and Ti[η5-C5(CH3)5]2Cl, have enabled derivation of titanium-carbon and titanium-chlorine stepwise bond dissociation enthalpies in these species.",

author = "Dias, {Alberto R.} and Salema, {Margarida S.} and {Martinho Sim{\~o}es}, {Jose A.} and Pattiasina, {Johannes W.} and Teuben, {Jan H.}",

note = "Relation: http://www.rug.nl/scheikunde/ date_submitted:2005 Rights: University of Groningen. Stratingh Institute",

year = "1988",

month = may,

day = "17",

doi = "10.1016/0022-328X(88)87013-X",

language = "English",

volume = "346",

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journal = "Journal of Organometallic Chemistry",

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Stepwise Ti-Cl, Ti-CH3, and Ti-C6H5 bond dissociation enthalpies in bis(pentamethylcyclopentadienyl)titanium complexes. / Dias, Alberto R.; Salema, Margarida S.; Martinho Simões, Jose A.; Pattiasina, Johannes W.; Teuben, Jan H.

In: Journal of Organometallic Chemistry, Vol. 346, No. 1, 17.05.1988, p. C4-C6.

Research output: Contribution to journal › Article › Academic › peer-review

TY - JOUR

T1 - Stepwise Ti-Cl, Ti-CH3, and Ti-C6H5 bond dissociation enthalpies in bis(pentamethylcyclopentadienyl)titanium complexes

AU - Dias, Alberto R.

AU - Salema, Margarida S.

AU - Martinho Simões, Jose A.

AU - Pattiasina, Johannes W.

AU - Teuben, Jan H.

N1 - Relation: http://www.rug.nl/scheikunde/ date_submitted:2005 Rights: University of Groningen. Stratingh Institute

PY - 1988/5/17

Y1 - 1988/5/17

N2 - Reaction-solution calorimetric studies involving the complexes Ti[η5-C5(CH3)5]2(CH3)2, Ti[η5-C5(CH3)5]2(CH3), Ti[η5-C5(CH3)5]2(C6H5), Ti[η5-C5(CH3)5]2Cl2, and Ti[η5-C5(CH3)5]2Cl, have enabled derivation of titanium-carbon and titanium-chlorine stepwise bond dissociation enthalpies in these species.

AB - Reaction-solution calorimetric studies involving the complexes Ti[η5-C5(CH3)5]2(CH3)2, Ti[η5-C5(CH3)5]2(CH3), Ti[η5-C5(CH3)5]2(C6H5), Ti[η5-C5(CH3)5]2Cl2, and Ti[η5-C5(CH3)5]2Cl, have enabled derivation of titanium-carbon and titanium-chlorine stepwise bond dissociation enthalpies in these species.

U2 - 10.1016/0022-328X(88)87013-X

DO - 10.1016/0022-328X(88)87013-X

M3 - Article

VL - 346

SP - C4-C6

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

SN - 0022-328X

IS - 1

ER -