Stepwise Ti-Cl, Ti-CH3, and Ti-C6H5 bond dissociation enthalpies in bis(pentamethylcyclopentadienyl)titanium complexes

Alberto R. Dias, Margarida S. Salema, Jose A. Martinho Simões, Johannes W. Pattiasina, Jan H. Teuben

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Abstract

Reaction-solution calorimetric studies involving the complexes Ti[η5-C5(CH3)5]2(CH3)2, Ti[η5-C5(CH3)5]2(CH3), Ti[η5-C5(CH3)5]2(C6H5), Ti[η5-C5(CH3)5]2Cl2, and Ti[η5-C5(CH3)5]2Cl, have enabled derivation of titanium-carbon and titanium-chlorine stepwise bond dissociation enthalpies in these species.
Original languageEnglish
Pages (from-to)C4-C6
Number of pages3
JournalJournal of Organometallic Chemistry
Volume346
Issue number1
DOIs
Publication statusPublished - 17-May-1988

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