Structural Disorder as the Origin of Optical Properties and Spectral Dynamics in Squaraine Nano-Aggregates

Robin Bernhardt*, Marìck Manrho, Jennifer Zablocki, Lukas Rieland, Arne Lützen, Manuela Schiek, Klaus Meerholz, Jingyi Zhu*, Thomas L.C. Jansen, Jasper Knoester, Paul H.M. Van Loosdrecht*

*Corresponding author for this work

Research output: Contribution to journalArticleAcademicpeer-review

10 Citations (Scopus)
178 Downloads (Pure)

Abstract

In contrast to regular J- and H-aggregates, thin film squaraine aggregates usually have broad absorption spectra containing both J-and H-like features, which are favorable for organic photovoltaics. Despite being successfully applied in organic photovoltaics for years, a clear interpretation of these optical properties by relating them to specific excited states and an underlying aggregate structure has not been made. In this work, by static and transient absorption spectroscopy on aggregated n-butyl anilino squaraines, we provide evidence that both the red- and blue-shifted peaks can be explained by assuming an ensemble of aggregates with intermolecular dipole-dipole resonance interactions and structural disorder deriving from the four different nearest neighbor alignments-in sharp contrast to previous association of the peaks with intermolecular charge-transfer interactions. In our model, the next-nearest neighbor dipole-dipole interactions may be negative or positive, which leads to the occurrence of J- and H-like features in the absorption spectrum. Upon femtosecond pulse excitation of the aggregated sample, a transient absorption spectrum deviating from the absorbance spectrum emerges. The deviation finds its origin in the excitation of two-exciton states by the probe pulse. The lifetime of the exciton is confirmed by the band integral dynamics, featuring a single-exponential decay with a lifetime of 205 ps. Our results disclose the aggregated structure and the origin of red- and blue-shifted peaks and explain the absence of photoluminescence in squaraine thin films. Our findings underline the important role of structural disorder of molecular aggregates for photovoltaic applications.

Original languageEnglish
Pages (from-to)19372–19381
Number of pages10
JournalJournal of the American Chemical Society
Volume144
Issue number42
DOIs
Publication statusPublished - 26-Oct-2022

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