TY - JOUR
T1 - Structural Disorder as the Origin of Optical Properties and Spectral Dynamics in Squaraine Nano-Aggregates
AU - Bernhardt, Robin
AU - Manrho, Marìck
AU - Zablocki, Jennifer
AU - Rieland, Lukas
AU - Lützen, Arne
AU - Schiek, Manuela
AU - Meerholz, Klaus
AU - Zhu, Jingyi
AU - Jansen, Thomas L.C.
AU - Knoester, Jasper
AU - Van Loosdrecht, Paul H.M.
N1 - Funding Information:
The authors gratefully acknowledge support from the Deutsche Forschungsgemeinschaft (DFG, RTG-2591 “TIDE─Template-designed Organic Electronics”). M.S. thanks the PRO RETINA Foundation as well as the Linz Institute of Technology (LIT-2019-7-INC-313 SEAMBIOF) for funding.
Publisher Copyright:
© 2022 American Chemical Society. All rights reserved.
PY - 2022/10/26
Y1 - 2022/10/26
N2 - In contrast to regular J- and H-aggregates, thin film squaraine aggregates usually have broad absorption spectra containing both J-and H-like features, which are favorable for organic photovoltaics. Despite being successfully applied in organic photovoltaics for years, a clear interpretation of these optical properties by relating them to specific excited states and an underlying aggregate structure has not been made. In this work, by static and transient absorption spectroscopy on aggregated n-butyl anilino squaraines, we provide evidence that both the red- and blue-shifted peaks can be explained by assuming an ensemble of aggregates with intermolecular dipole-dipole resonance interactions and structural disorder deriving from the four different nearest neighbor alignments-in sharp contrast to previous association of the peaks with intermolecular charge-transfer interactions. In our model, the next-nearest neighbor dipole-dipole interactions may be negative or positive, which leads to the occurrence of J- and H-like features in the absorption spectrum. Upon femtosecond pulse excitation of the aggregated sample, a transient absorption spectrum deviating from the absorbance spectrum emerges. The deviation finds its origin in the excitation of two-exciton states by the probe pulse. The lifetime of the exciton is confirmed by the band integral dynamics, featuring a single-exponential decay with a lifetime of 205 ps. Our results disclose the aggregated structure and the origin of red- and blue-shifted peaks and explain the absence of photoluminescence in squaraine thin films. Our findings underline the important role of structural disorder of molecular aggregates for photovoltaic applications.
AB - In contrast to regular J- and H-aggregates, thin film squaraine aggregates usually have broad absorption spectra containing both J-and H-like features, which are favorable for organic photovoltaics. Despite being successfully applied in organic photovoltaics for years, a clear interpretation of these optical properties by relating them to specific excited states and an underlying aggregate structure has not been made. In this work, by static and transient absorption spectroscopy on aggregated n-butyl anilino squaraines, we provide evidence that both the red- and blue-shifted peaks can be explained by assuming an ensemble of aggregates with intermolecular dipole-dipole resonance interactions and structural disorder deriving from the four different nearest neighbor alignments-in sharp contrast to previous association of the peaks with intermolecular charge-transfer interactions. In our model, the next-nearest neighbor dipole-dipole interactions may be negative or positive, which leads to the occurrence of J- and H-like features in the absorption spectrum. Upon femtosecond pulse excitation of the aggregated sample, a transient absorption spectrum deviating from the absorbance spectrum emerges. The deviation finds its origin in the excitation of two-exciton states by the probe pulse. The lifetime of the exciton is confirmed by the band integral dynamics, featuring a single-exponential decay with a lifetime of 205 ps. Our results disclose the aggregated structure and the origin of red- and blue-shifted peaks and explain the absence of photoluminescence in squaraine thin films. Our findings underline the important role of structural disorder of molecular aggregates for photovoltaic applications.
UR - http://www.scopus.com/inward/record.url?scp=85140481706&partnerID=8YFLogxK
U2 - 10.1021/jacs.2c07064
DO - 10.1021/jacs.2c07064
M3 - Article
C2 - 36240390
AN - SCOPUS:85140481706
SN - 0002-7863
VL - 144
SP - 19372
EP - 19381
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
IS - 42
ER -