Structure of 2,2'-(2,4-pyrimidinediyldi­oxy)bis­(2,4,4,6,6-penta­chloro-1,3,5,2λ5,4λ5,6λ5-tri­azatri­phosphorine) at 130 K

F. van Bolhuis, A. Meetsma, J. C. van de Grampel, K. Brandt

Research output: Contribution to journalArticleAcademicpeer-review

Abstract

C4H2Cl10N8O2P6, M(r) = 734.48, monoclinic, P2(1)/a, a = 8.365 (8), b = 22.654 (2), c = 13.436 (5) angstrom, beta = 107.70 (5)-degrees, V = 2426 (3) angstrom 3, Z = 4, D(x) = 2.011 g cm-3, lambda(Mo K-alphaBAR) = 0.71073, mu = 15.7 cm-1, F(000) = 1432, T = 130 K, R(F) = 0.026 for 3530 unique reflections with I greater-than-or-equal-to 3-sigma(I) and 279 parameters. The molecule consists of two N3P3Cl5 fragments coupled together by a pyrimidinediyldioxy group via P-O-C bridges. The mean P-N bond length is 1.579 (1) angstrom, the P-Cl bond lengths vary from 1.976 (2) to 2.003 (2) angstrom. The lengths of the N-C bonds [1.316 (5)-1.343 (5) angstrom] and C-C bonds [mean value 1.380 (7) angstrom] reflect the aromatic character of the organic heterocycle.
Original languageEnglish
Pages (from-to)337-339
Number of pages3
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume48
DOIs
Publication statusPublished - 15-Feb-1992

Cite this