Structure of ethyl 2,4,4,6,6-penta­chloro-1,3,5,2λ5,4λ5,6λ5-tri­azatriphosphinine-2-carbamate

A. Meetsma; P. L. Buwalda; J. C. van de Grampel

doi:10.1107/S0108270189010164

Structure of ethyl 2,4,4,6,6-pentachloro-1,3,5,2λ5,4λ5,6λ5-triazatriphosphinine-2-carbamate

A. Meetsma
, P. L. Buwalda
, J. C. van de Grampel

Polymer Chemistry and Bioengineering

Research output: Contribution to journal › Article › Academic › peer-review

Abstract

C3H6CI5N402P3, Mr = 400"29, orthorhombic, Pnnm, a=9.195(2), b = 14-348(3), c= 11.351 (1) A, V= 1497.5 (5) A 3, Z= 4, Dx = 1.775 g cm -3, A(Mo K~) = 0-71073 A, /z = 12.8 cm-l, F(000) = 792, T = 298 K, Rr = 0-042 for 1035 reflections with I_> 2.5cr(/). The crystal structure consists of dimers arising from hydrogen-bond bridges. The organic moiety is located close to the NP ring. The endocyclic N--P bond lengths average to 1-570 (5) A; N--P (exocyclic) = 1.662 (6) A. The P--CI bond lengths vary from 1.974(2) to 2.007 (3) A.

Original language	English
Pages (from-to)	886-888
Number of pages	3
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	46
DOIs	https://doi.org/10.1107/S0108270189010164
Publication status	Published - 15-May-1990

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Structure of ethyl 2,4,4,6,6-pentachloro-1,3,5,2λ5,4λ5,6λ5-triazatriphosphinine-2-carbamate
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@article{ec72b2b9041a426cb44407339fab7570,

title = "Structure of ethyl 2,4,4,6,6-pentachloro-1,3,5,2λ5,4λ5,6λ5-triazatriphosphinine-2-carbamate",

abstract = "C3H6CI5N402P3, Mr = 400{"}29, orthorhombic, Pnnm, a=9.195(2), b = 14-348(3), c= 11.351 (1) A, V= 1497.5 (5) A 3, Z= 4, Dx = 1.775 g cm -3, A(Mo K\textasciitilde{}) = 0-71073 A, /z = 12.8 cm-l, F(000) = 792, T = 298 K, Rr = 0-042 for 1035 reflections with I\_> 2.5cr(/). The crystal structure consists of dimers arising from hydrogen-bond bridges. The organic moiety is located close to the NP ring. The endocyclic N--P bond lengths average to 1-570 (5) A; N--P (exocyclic) = 1.662 (6) A. The P--CI bond lengths vary from 1.974(2) to 2.007 (3) A. ",

author = "A. Meetsma and Buwalda, \{P. L.\} and \{van de Grampel\}, \{J. C.\}",

year = "1990",

month = may,

day = "15",

doi = "10.1107/S0108270189010164",

language = "English",

volume = "46",

pages = "886--888",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

}

TY - JOUR

T1 - Structure of ethyl 2,4,4,6,6-pentachloro-1,3,5,2λ5,4λ5,6λ5-triazatriphosphinine-2-carbamate

AU - Meetsma, A.

AU - Buwalda, P. L.

AU - van de Grampel, J. C.

PY - 1990/5/15

Y1 - 1990/5/15

N2 - C3H6CI5N402P3, Mr = 400"29, orthorhombic, Pnnm, a=9.195(2), b = 14-348(3), c= 11.351 (1) A, V= 1497.5 (5) A 3, Z= 4, Dx = 1.775 g cm -3, A(Mo K~) = 0-71073 A, /z = 12.8 cm-l, F(000) = 792, T = 298 K, Rr = 0-042 for 1035 reflections with I_> 2.5cr(/). The crystal structure consists of dimers arising from hydrogen-bond bridges. The organic moiety is located close to the NP ring. The endocyclic N--P bond lengths average to 1-570 (5) A; N--P (exocyclic) = 1.662 (6) A. The P--CI bond lengths vary from 1.974(2) to 2.007 (3) A.

AB - C3H6CI5N402P3, Mr = 400"29, orthorhombic, Pnnm, a=9.195(2), b = 14-348(3), c= 11.351 (1) A, V= 1497.5 (5) A 3, Z= 4, Dx = 1.775 g cm -3, A(Mo K~) = 0-71073 A, /z = 12.8 cm-l, F(000) = 792, T = 298 K, Rr = 0-042 for 1035 reflections with I_> 2.5cr(/). The crystal structure consists of dimers arising from hydrogen-bond bridges. The organic moiety is located close to the NP ring. The endocyclic N--P bond lengths average to 1-570 (5) A; N--P (exocyclic) = 1.662 (6) A. The P--CI bond lengths vary from 1.974(2) to 2.007 (3) A.

U2 - 10.1107/S0108270189010164

DO - 10.1107/S0108270189010164

M3 - Article

SN - 0108-2701

VL - 46

SP - 886

EP - 888

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

ER -