Structure of trans-5-iso­propyl-1,3-di­phenyl-5-propyl-1λ6,3λ6,2,4,6,5λ5-di­thiatri­aza­phosphorine 1,3-dioxide

A. Meetsma; A. L. Spek; H. Winter; J. C. van de Grampel; J. L. de Boer

doi:10.1107/S0108270186096154

Structure of trans-5-isopropyl-1,3-diphenyl-5-propyl-1λ6,3λ6,2,4,6,5λ5-dithiatriazaphosphorine 1,3-dioxide

A. Meetsma, A. L. Spek, H. Winter, J. C. van de Grampel, J. L. de Boer

Research output: Contribution to journal › Article › Academic › peer-review

Abstract

C18H24N302PS2, Mr=409.5 , monoclinic, P21/n, a = 13.432 (6), b = 16.727 (4), c = 9.602 (2) A, fl=110.21(3) ° , V=2025(1)A 3, Z=4, Dx= 1.343 gcm -3, 2(Mo K~) = 0.71073 A, /L = 3.5 cm -~, F(000) = 864, T- 295 K, R = 0.053 for 1628 observed reflections. The inorganic ring possesses a twistboat conformation with the phenyl substituents in trans positions. Mean bond lengths are N-P = 1.608 (3), N-S (from segment SNS)= 1.568 (4), N-S (from segment PNS)= 1.544 (3)A. The average endocyclic angles at S and N are 114.3 (2) and 124.4(5) ° respectively. The endocyclic angle at P amounts to 113.0(2) ° .

Original language	English
Pages (from-to)	368-371
Number of pages	4
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	42
DOIs	https://doi.org/10.1107/S0108270186096154
Publication status	Published - 15-Mar-1986

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Structure of trans-5-1sopropyl- 1,3-diphenyl-5-p
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@article{0d1b09a257fd44b389a011b3857ad586,

title = "Structure of trans-5-isopropyl-1,3-diphenyl-5-propyl-1λ6,3λ6,2,4,6,5λ5-dithiatriazaphosphorine 1,3-dioxide",

abstract = "C18H24N302PS2, Mr=409.5 , monoclinic, P21/n, a = 13.432 (6), b = 16.727 (4), c = 9.602 (2) A, fl=110.21(3) ° , V=2025(1)A 3, Z=4, Dx= 1.343 gcm -3, 2(Mo K~) = 0.71073 A, /L = 3.5 cm -~, F(000) = 864, T- 295 K, R = 0.053 for 1628 observed reflections. The inorganic ring possesses a twistboat conformation with the phenyl substituents in trans positions. Mean bond lengths are N-P = 1.608 (3), N-S (from segment SNS)= 1.568 (4), N-S (from segment PNS)= 1.544 (3)A. The average endocyclic angles at S and N are 114.3 (2) and 124.4(5) ° respectively. The endocyclic angle at P amounts to 113.0(2) ° . ",

author = "A. Meetsma and Spek, {A. L.} and H. Winter and {van de Grampel}, {J. C.} and {de Boer}, {J. L.}",

year = "1986",

month = mar,

day = "15",

doi = "10.1107/S0108270186096154",

language = "English",

volume = "42",

pages = "368--371",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

}

Structure of trans-5-isopropyl-1,3-diphenyl-5-propyl-1λ6,3λ6,2,4,6,5λ5-dithiatriazaphosphorine 1,3-dioxide. / Meetsma, A.; Spek, A. L.; Winter, H.; van de Grampel, J. C.; de Boer, J. L.

In: Acta Crystallographica Section C: Crystal Structure Communications, Vol. 42, 15.03.1986, p. 368-371.

Research output: Contribution to journal › Article › Academic › peer-review

TY - JOUR

T1 - Structure of trans-5-isopropyl-1,3-diphenyl-5-propyl-1λ6,3λ6,2,4,6,5λ5-dithiatriazaphosphorine 1,3-dioxide

AU - Meetsma, A.

AU - Spek, A. L.

AU - Winter, H.

AU - van de Grampel, J. C.

AU - de Boer, J. L.

PY - 1986/3/15

Y1 - 1986/3/15

N2 - C18H24N302PS2, Mr=409.5 , monoclinic, P21/n, a = 13.432 (6), b = 16.727 (4), c = 9.602 (2) A, fl=110.21(3) ° , V=2025(1)A 3, Z=4, Dx= 1.343 gcm -3, 2(Mo K~) = 0.71073 A, /L = 3.5 cm -~, F(000) = 864, T- 295 K, R = 0.053 for 1628 observed reflections. The inorganic ring possesses a twistboat conformation with the phenyl substituents in trans positions. Mean bond lengths are N-P = 1.608 (3), N-S (from segment SNS)= 1.568 (4), N-S (from segment PNS)= 1.544 (3)A. The average endocyclic angles at S and N are 114.3 (2) and 124.4(5) ° respectively. The endocyclic angle at P amounts to 113.0(2) ° .

AB - C18H24N302PS2, Mr=409.5 , monoclinic, P21/n, a = 13.432 (6), b = 16.727 (4), c = 9.602 (2) A, fl=110.21(3) ° , V=2025(1)A 3, Z=4, Dx= 1.343 gcm -3, 2(Mo K~) = 0.71073 A, /L = 3.5 cm -~, F(000) = 864, T- 295 K, R = 0.053 for 1628 observed reflections. The inorganic ring possesses a twistboat conformation with the phenyl substituents in trans positions. Mean bond lengths are N-P = 1.608 (3), N-S (from segment SNS)= 1.568 (4), N-S (from segment PNS)= 1.544 (3)A. The average endocyclic angles at S and N are 114.3 (2) and 124.4(5) ° respectively. The endocyclic angle at P amounts to 113.0(2) ° .

U2 - 10.1107/S0108270186096154

DO - 10.1107/S0108270186096154

M3 - Article

VL - 42

SP - 368

EP - 371

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications