Synthesis and characterization of bis(eta(5)-1,2,3,4,5-pentamethylcyclopentadienyl)(eta(3)-1-phenylallyl)lanthanum center dot tetrahydrofuran

Winfried P. Kretschmer; Bas ten Brummelhuis; Auke Meetsma; Jan H. Teuben

doi:10.1002/zaac.200600141

Synthesis and characterization of bis(eta(5)-1,2,3,4,5-pentamethylcyclopentadienyl)(eta(3)-1-phenylallyl)lanthanum center dot tetrahydrofuran

Winfried P. Kretschmer^*, Bas ten Brummelhuis, Auke Meetsma, Jan H. Teuben

^*Corresponding author for this work

Research output: Contribution to journal › Article › Academic › peer-review

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Abstract

Original language	English
Pages (from-to)	1933-1935
Number of pages	3
Journal	Zeitschrift fur Anorganische und Allgemeine Chemie
Volume	632
Issue number	12-13
DOIs	https://doi.org/10.1002/zaac.200600141
Publication status	Published - 2006
Event	Rare Earths 2005 Conference - , Germany Duration: 30-Nov-2005 → 2-Dec-2005

Keywords

lanthanum
lanthanides
allyl complexes
NMR spectroscopy
POLYMERIZATION CATALYSTS
OLEFIN POLYMERIZATION
METAL-CATALYSTS
REACTIVITY
COMPLEXES
ISOPRENE
ETHYLENE
ORGANOLANTHANIDES
SYSTEMS

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CCDC 114668: Experimental Crystal Structure Determination
Kretschmer, W. (Contributor), Ten Brummelhuis, B. (Contributor), Meetsma, A. (Contributor) & Teuben, J. (Contributor), University of Groningen, 12-Feb-1999
DOI: 10.5517/cc3v9z6
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@article{fbdb941b53ff49b7b04a89108aa48e63,

title = "Synthesis and characterization of bis(eta(5)-1,2,3,4,5-pentamethylcyclopentadienyl)(eta(3)-1-phenylallyl)lanthanum center dot tetrahydrofuran",

abstract = "The title compound has been prepared from Cp-2*LaCl2K(THF)(2) and 1-PhC3H4K-(THF)(0.5) in THF suspension, forming yellow single crystals from hexane solution which were characterized in solid state and in solution by elementary analysis, IR, C-13- and variable temperature H-1-NMR spectroscopy and a crystal structure determination. Space group P1, Z = 2, T = 130 K, a = 8.595(1), b = 10.770(1), c = 17.903(5) angstrom, alpha = 93.54(1)degrees, beta = 98.30(1)degrees, gamma = 112.42(1)degrees, R = 0.0249.",

keywords = "lanthanum, lanthanides, allyl complexes, NMR spectroscopy, POLYMERIZATION CATALYSTS, OLEFIN POLYMERIZATION, METAL-CATALYSTS, REACTIVITY, COMPLEXES, ISOPRENE, ETHYLENE, ORGANOLANTHANIDES, SYSTEMS",

author = "Kretschmer, {Winfried P.} and {ten Brummelhuis}, Bas and Auke Meetsma and Teuben, {Jan H.}",

note = "Cited By (since 1996): 1; Rare Earths 2005 Conference ; Conference date: 30-11-2005 Through 02-12-2005",

year = "2006",

doi = "10.1002/zaac.200600141",

language = "English",

volume = "632",

pages = "1933--1935",

journal = "Zeitschrift fur Anorganische und Allgemeine Chemie",

issn = "0044-2313",

publisher = "WILEY-V C H VERLAG GMBH",

number = "12-13",

}

Synthesis and characterization of bis(eta(5)-1,2,3,4,5-pentamethylcyclopentadienyl)(eta(3)-1-phenylallyl)lanthanum center dot tetrahydrofuran. / Kretschmer, Winfried P.; ten Brummelhuis, Bas; Meetsma, Auke et al.
In: Zeitschrift fur Anorganische und Allgemeine Chemie, Vol. 632, No. 12-13, 2006, p. 1933-1935.

Research output: Contribution to journal › Article › Academic › peer-review

TY - JOUR

T1 - Synthesis and characterization of bis(eta(5)-1,2,3,4,5-pentamethylcyclopentadienyl)(eta(3)-1-phenylallyl)lanthanum center dot tetrahydrofuran

AU - Kretschmer, Winfried P.

AU - ten Brummelhuis, Bas

AU - Meetsma, Auke

AU - Teuben, Jan H.

N1 - Cited By (since 1996): 1

PY - 2006

Y1 - 2006

N2 - The title compound has been prepared from Cp-2*LaCl2K(THF)(2) and 1-PhC3H4K-(THF)(0.5) in THF suspension, forming yellow single crystals from hexane solution which were characterized in solid state and in solution by elementary analysis, IR, C-13- and variable temperature H-1-NMR spectroscopy and a crystal structure determination. Space group P1, Z = 2, T = 130 K, a = 8.595(1), b = 10.770(1), c = 17.903(5) angstrom, alpha = 93.54(1)degrees, beta = 98.30(1)degrees, gamma = 112.42(1)degrees, R = 0.0249.

AB - The title compound has been prepared from Cp-2*LaCl2K(THF)(2) and 1-PhC3H4K-(THF)(0.5) in THF suspension, forming yellow single crystals from hexane solution which were characterized in solid state and in solution by elementary analysis, IR, C-13- and variable temperature H-1-NMR spectroscopy and a crystal structure determination. Space group P1, Z = 2, T = 130 K, a = 8.595(1), b = 10.770(1), c = 17.903(5) angstrom, alpha = 93.54(1)degrees, beta = 98.30(1)degrees, gamma = 112.42(1)degrees, R = 0.0249.

KW - lanthanum

KW - lanthanides

KW - allyl complexes

KW - NMR spectroscopy

KW - POLYMERIZATION CATALYSTS

KW - OLEFIN POLYMERIZATION

KW - METAL-CATALYSTS

KW - REACTIVITY

KW - COMPLEXES

KW - ISOPRENE

KW - ETHYLENE

KW - ORGANOLANTHANIDES

KW - SYSTEMS

U2 - 10.1002/zaac.200600141

DO - 10.1002/zaac.200600141

M3 - Article

SN - 0044-2313

VL - 632

SP - 1933

EP - 1935

JO - Zeitschrift fur Anorganische und Allgemeine Chemie

JF - Zeitschrift fur Anorganische und Allgemeine Chemie

IS - 12-13

T2 - Rare Earths 2005 Conference

Y2 - 30 November 2005 through 2 December 2005

ER -

Synthesis and characterization of bis(eta(5)-1,2,3,4,5-pentamethylcyclopentadienyl)(eta(3)-1-phenylallyl)lanthanum center dot tetrahydrofuran

Abstract

Keywords

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Datasets

CCDC 114668: Experimental Crystal Structure Determination

Cite this