Synthesis of functionalized molecular motors

MKJ ter Wiel; BL Feringa

doi:10.1055/s-2005-869954

Synthesis of functionalized molecular motors

MKJ ter Wiel, BL Feringa^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › Academic › peer-review

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Abstract

Synthetic routes to two molecular motors are reported. The sterically hindered central olefinic bond connecting the two halves of these C,symmetric molecules was prepared by a McMurry reaction. In this way, a motor with two five-membered rings and a motor with two six-membered rings were prepared, both with two versatile methoxy substituents at positions not interfering with the rotary behavior.

Original language	English
Pages (from-to)	1789-1796
Number of pages	8
Journal	Synthesis-Stuttgart
Volume	2005
Issue number	11
DOIs	https://doi.org/10.1055/s-2005-869954
Publication status	Published - 15-Jul-2005

Keywords

alkenes
arenes
nanostructures
McMurry reactions
SINGLE STEREOGENIC CENTER
ROTATION
MOTION
SPEED
ROTOR

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title = "Synthesis of functionalized molecular motors",

abstract = "Synthetic routes to two molecular motors are reported. The sterically hindered central olefinic bond connecting the two halves of these C,symmetric molecules was prepared by a McMurry reaction. In this way, a motor with two five-membered rings and a motor with two six-membered rings were prepared, both with two versatile methoxy substituents at positions not interfering with the rotary behavior.",

keywords = "alkenes, arenes, nanostructures, McMurry reactions, SINGLE STEREOGENIC CENTER, ROTATION, MOTION, SPEED, ROTOR",

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T1 - Synthesis of functionalized molecular motors

AU - ter Wiel, MKJ

AU - Feringa, BL

PY - 2005/7/15

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N2 - Synthetic routes to two molecular motors are reported. The sterically hindered central olefinic bond connecting the two halves of these C,symmetric molecules was prepared by a McMurry reaction. In this way, a motor with two five-membered rings and a motor with two six-membered rings were prepared, both with two versatile methoxy substituents at positions not interfering with the rotary behavior.

AB - Synthetic routes to two molecular motors are reported. The sterically hindered central olefinic bond connecting the two halves of these C,symmetric molecules was prepared by a McMurry reaction. In this way, a motor with two five-membered rings and a motor with two six-membered rings were prepared, both with two versatile methoxy substituents at positions not interfering with the rotary behavior.

KW - alkenes

KW - arenes

KW - nanostructures

KW - McMurry reactions

KW - SINGLE STEREOGENIC CENTER

KW - ROTATION

KW - MOTION

KW - SPEED

KW - ROTOR

U2 - 10.1055/s-2005-869954

DO - 10.1055/s-2005-869954

M3 - Article

SN - 1437-210X

VL - 2005

SP - 1789

EP - 1796

JO - Synthesis-Stuttgart

JF - Synthesis-Stuttgart

IS - 11

ER -

Synthesis of functionalized molecular motors

Abstract

Keywords

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