The control of the growth of Pt clusters in solution: A way to prepare Pt particles of tailored size

Gloria Uccello-Barretta; Claudio Evangelisti; Patrizio Raffa; Federica Balzano; Samuele Nazzi; Gianmario Martra; Giovanni Vitulli; Piero Salvadori

doi:10.1016/j.jorganchem.2009.01.010

The control of the growth of Pt clusters in solution: A way to prepare Pt particles of tailored size

Gloria Uccello-Barretta^*, Claudio Evangelisti, Patrizio Raffa, Federica Balzano, Samuele Nazzi, Gianmario Martra, Giovanni Vitulli, Piero Salvadori

^*Corresponding author for this work

Research output: Contribution to journal › Article › Academic › peer-review

10 Citations (Scopus)

Abstract

The growth of Pt particles in mesitylene-solvated metal atoms, obtained by metal vapour synthesis (MVS), has been followed at two temperatures (-40 and 25 degrees C) by NMR DOSY technique. The addition of 1,3-divinyltetramethyldisiloxane (DVS) at different time allows to quench the growth process and to make the resulting thermally stable solutions suitable for the evaluation of the Pt particles size at that moment. These solutions can be conveniently used to prepare supported Pt systems containing Pt particles of tailored size. (C) 2009 Elsevier B.V. All rights reserved.

Original language	English
Pages (from-to)	1813-1817
Number of pages	5
Journal	Journal of Organometallic Chemistry
Volume	694
Issue number	12
DOIs	https://doi.org/10.1016/j.jorganchem.2009.01.010
Publication status	Published - 15-May-2009
Externally published	Yes

Keywords

MVS synthesis
DOSY
NMR
Pt nanoparticles
NANOPARTICLE GROWTH
MECHANISM
NANOCRYSTALS
NUCLEATION
DIFFUSION
HYDROGEN

Access to Document

10.1016/j.jorganchem.2009.01.010

Cite this

@article{d3494ffe9dc54773a1613ccfdb92be5b,

title = "The control of the growth of Pt clusters in solution: A way to prepare Pt particles of tailored size",

abstract = "The growth of Pt particles in mesitylene-solvated metal atoms, obtained by metal vapour synthesis (MVS), has been followed at two temperatures (-40 and 25 degrees C) by NMR DOSY technique. The addition of 1,3-divinyltetramethyldisiloxane (DVS) at different time allows to quench the growth process and to make the resulting thermally stable solutions suitable for the evaluation of the Pt particles size at that moment. These solutions can be conveniently used to prepare supported Pt systems containing Pt particles of tailored size. (C) 2009 Elsevier B.V. All rights reserved.",

keywords = "MVS synthesis, DOSY, NMR, Pt nanoparticles, NANOPARTICLE GROWTH, MECHANISM, NANOCRYSTALS, NUCLEATION, DIFFUSION, HYDROGEN",

author = "Gloria Uccello-Barretta and Claudio Evangelisti and Patrizio Raffa and Federica Balzano and Samuele Nazzi and Gianmario Martra and Giovanni Vitulli and Piero Salvadori",

year = "2009",

month = may,

day = "15",

doi = "10.1016/j.jorganchem.2009.01.010",

language = "English",

volume = "694",

pages = "1813--1817",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

number = "12",

}

The control of the growth of Pt clusters in solution : A way to prepare Pt particles of tailored size. / Uccello-Barretta, Gloria; Evangelisti, Claudio; Raffa, Patrizio; Balzano, Federica; Nazzi, Samuele; Martra, Gianmario; Vitulli, Giovanni; Salvadori, Piero.

In: Journal of Organometallic Chemistry, Vol. 694, No. 12, 15.05.2009, p. 1813-1817.

Research output: Contribution to journal › Article › Academic › peer-review

TY - JOUR

T1 - The control of the growth of Pt clusters in solution

T2 - A way to prepare Pt particles of tailored size

AU - Uccello-Barretta, Gloria

AU - Evangelisti, Claudio

AU - Raffa, Patrizio

AU - Balzano, Federica

AU - Nazzi, Samuele

AU - Martra, Gianmario

AU - Vitulli, Giovanni

AU - Salvadori, Piero

PY - 2009/5/15

Y1 - 2009/5/15

N2 - The growth of Pt particles in mesitylene-solvated metal atoms, obtained by metal vapour synthesis (MVS), has been followed at two temperatures (-40 and 25 degrees C) by NMR DOSY technique. The addition of 1,3-divinyltetramethyldisiloxane (DVS) at different time allows to quench the growth process and to make the resulting thermally stable solutions suitable for the evaluation of the Pt particles size at that moment. These solutions can be conveniently used to prepare supported Pt systems containing Pt particles of tailored size. (C) 2009 Elsevier B.V. All rights reserved.

AB - The growth of Pt particles in mesitylene-solvated metal atoms, obtained by metal vapour synthesis (MVS), has been followed at two temperatures (-40 and 25 degrees C) by NMR DOSY technique. The addition of 1,3-divinyltetramethyldisiloxane (DVS) at different time allows to quench the growth process and to make the resulting thermally stable solutions suitable for the evaluation of the Pt particles size at that moment. These solutions can be conveniently used to prepare supported Pt systems containing Pt particles of tailored size. (C) 2009 Elsevier B.V. All rights reserved.

KW - MVS synthesis

KW - DOSY

KW - NMR

KW - Pt nanoparticles

KW - NANOPARTICLE GROWTH

KW - MECHANISM

KW - NANOCRYSTALS

KW - NUCLEATION

KW - DIFFUSION

KW - HYDROGEN

U2 - 10.1016/j.jorganchem.2009.01.010

DO - 10.1016/j.jorganchem.2009.01.010

M3 - Article

VL - 694

SP - 1813

EP - 1817

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

SN - 0022-328X

IS - 12

ER -