The effect of peripheral bipyridine ligands on the photocatalytic hydrogen production activity of Ru/Pd catalysts

Gurmeet Singh Bindra; Martin Schulz; Avishek Paul; Suraj Soman; Robert Groarke; Jane Inglis; Mary T. Pryce; Wesley R. Browne; Sven Rau; Brian J. Maclean; Johannes G. Vos

doi:10.1039/c1dt11241d

The effect of peripheral bipyridine ligands on the photocatalytic hydrogen production activity of Ru/Pd catalysts

Gurmeet Singh Bindra
, Martin Schulz
, Avishek Paul
, Suraj Soman
, Robert Groarke
, Jane Inglis
, Mary T. Pryce
, Wesley R. Browne
, Sven Rau
, Brian J. Maclean
, Johannes G. Vos^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › Academic › peer-review

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Abstract

A pyrazine bridged ruthenium/palladium bimetallic photocatalyst with peripheral 4,4'-dicarboxyethyl-2,2'-bipyridine ligands, EtOOC-RuPd, is reported, together with its 2,2'-bipyridine analogue. Upon irradiation with visible light, EtOOC-RuPd catalyses the production of hydrogen gas whereas the complex RuPd does not.

Original language	English
Pages (from-to)	10812-10814
Number of pages	3
Journal	Dalton Transactions
Volume	40
Issue number	41
DOIs	https://doi.org/10.1039/c1dt11241d
Publication status	Published - 2011

Keywords

RUTHENIUM(II) POLYPYRIDINE COMPLEXES
BRIDGING LIGANDS
SUPRAMOLECULAR PHOTOCATALYST
BUILDING-BLOCKS
CHARGE-TRANSFER
RU-II
ELECTROCHEMISTRY
DINUCLEAR
SYSTEM
WATER

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@article{9fb0219b66c04f72a1dd7506081c7efc,

title = "The effect of peripheral bipyridine ligands on the photocatalytic hydrogen production activity of Ru/Pd catalysts",

abstract = "A pyrazine bridged ruthenium/palladium bimetallic photocatalyst with peripheral 4,4'-dicarboxyethyl-2,2'-bipyridine ligands, EtOOC-RuPd, is reported, together with its 2,2'-bipyridine analogue. Upon irradiation with visible light, EtOOC-RuPd catalyses the production of hydrogen gas whereas the complex RuPd does not.",

keywords = "RUTHENIUM(II) POLYPYRIDINE COMPLEXES, BRIDGING LIGANDS, SUPRAMOLECULAR PHOTOCATALYST, BUILDING-BLOCKS, CHARGE-TRANSFER, RU-II, ELECTROCHEMISTRY, DINUCLEAR, SYSTEM, WATER",

author = "Bindra, \{Gurmeet Singh\} and Martin Schulz and Avishek Paul and Suraj Soman and Robert Groarke and Jane Inglis and Pryce, \{Mary T.\} and Browne, \{Wesley R.\} and Sven Rau and Maclean, \{Brian J.\} and Vos, \{Johannes G.\}",

year = "2011",

doi = "10.1039/c1dt11241d",

language = "English",

volume = "40",

pages = "10812--10814",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "ROYAL SOC CHEMISTRY",

number = "41",

}

TY - JOUR

T1 - The effect of peripheral bipyridine ligands on the photocatalytic hydrogen production activity of Ru/Pd catalysts

AU - Bindra, Gurmeet Singh

AU - Schulz, Martin

AU - Paul, Avishek

AU - Soman, Suraj

AU - Groarke, Robert

AU - Inglis, Jane

AU - Pryce, Mary T.

AU - Browne, Wesley R.

AU - Rau, Sven

AU - Maclean, Brian J.

AU - Vos, Johannes G.

PY - 2011

Y1 - 2011

N2 - A pyrazine bridged ruthenium/palladium bimetallic photocatalyst with peripheral 4,4'-dicarboxyethyl-2,2'-bipyridine ligands, EtOOC-RuPd, is reported, together with its 2,2'-bipyridine analogue. Upon irradiation with visible light, EtOOC-RuPd catalyses the production of hydrogen gas whereas the complex RuPd does not.

AB - A pyrazine bridged ruthenium/palladium bimetallic photocatalyst with peripheral 4,4'-dicarboxyethyl-2,2'-bipyridine ligands, EtOOC-RuPd, is reported, together with its 2,2'-bipyridine analogue. Upon irradiation with visible light, EtOOC-RuPd catalyses the production of hydrogen gas whereas the complex RuPd does not.

KW - RUTHENIUM(II) POLYPYRIDINE COMPLEXES

KW - BRIDGING LIGANDS

KW - SUPRAMOLECULAR PHOTOCATALYST

KW - BUILDING-BLOCKS

KW - CHARGE-TRANSFER

KW - RU-II

KW - ELECTROCHEMISTRY

KW - DINUCLEAR

KW - SYSTEM

KW - WATER

U2 - 10.1039/c1dt11241d

DO - 10.1039/c1dt11241d

M3 - Article

SN - 1477-9226

VL - 40

SP - 10812

EP - 10814

JO - Dalton Transactions

JF - Dalton Transactions

IS - 41

ER -

The effect of peripheral bipyridine ligands on the photocatalytic hydrogen production activity of Ru/Pd catalysts

Abstract

Keywords

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