The N,N '-bis(trimethylsilyl)pentafluorobenzamidinate ligand: enhanced ethene oligomerisation with a neutral V(III) bis(benzamidinate) alkyl catalyst

Edward A.C. Brussee; Auke Meetsma; Bart Hessen; Jan H. Teuben

doi:10.1039/b000397m

The N,N '-bis(trimethylsilyl)pentafluorobenzamidinate ligand: enhanced ethene oligomerisation with a neutral V(III) bis(benzamidinate) alkyl catalyst

Edward A.C. Brussee, Auke Meetsma, Bart Hessen, Jan H. Teuben

Research output: Contribution to journal › Article › Academic › peer-review

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Abstract

The pentafluorobenzamidinate ligand [C6F5C(NSiMe3)2]- is reported, together with its bis(benzamidinate) vanadium(III) methyl derivative; the latter is considerably more active in catalytic ethene oligomerisation than its non-fluorinated analogue.

Original language	English
Pages (from-to)	497-498
Number of pages	2
Journal	Chemical Communications
Volume	591
Issue number	6
DOIs	https://doi.org/10.1039/b000397m
Publication status	Published - 2000

Keywords

COORDINATION CHEMISTRY
POLYMERIZATION
COMPLEXES
ZIRCONIUM
TITANIUM

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CCDC 138322: Experimental Crystal Structure Determination
Brussee, E. (Contributor), Meetsma, A. (Contributor), Hessen, B. (Contributor) & Teuben, J. (Contributor), University of Groningen, 5-Apr-2000
DOI: 10.5517/cc4my0p
Dataset
CCDC 138323: Experimental Crystal Structure Determination
Brussee, E. (Contributor), Meetsma, A. (Contributor), Hessen, B. (Contributor) & Teuben, J. (Contributor), University of Groningen, 5-Apr-2000
DOI: 10.5517/cc4my1q
Dataset

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title = "The N,N '-bis(trimethylsilyl)pentafluorobenzamidinate ligand: enhanced ethene oligomerisation with a neutral V(III) bis(benzamidinate) alkyl catalyst",

abstract = "The pentafluorobenzamidinate ligand [C6F5C(NSiMe3)2]- is reported, together with its bis(benzamidinate) vanadium(III) methyl derivative; the latter is considerably more active in catalytic ethene oligomerisation than its non-fluorinated analogue.",

keywords = "COORDINATION CHEMISTRY, POLYMERIZATION, COMPLEXES, ZIRCONIUM, TITANIUM",

author = "Brussee, {Edward A.C.} and Auke Meetsma and Bart Hessen and Teuben, {Jan H.}",

note = "Relation: http://www.rug.nl/scheikunde/ date_submitted:2005 Rights: University of Groningen. Stratingh Institute",

year = "2000",

doi = "10.1039/b000397m",

language = "English",

volume = "591",

pages = "497--498",

journal = "Chemical Communications (Cambridge, United Kingdom)",

issn = "1359-7345",

publisher = "ROYAL SOC CHEMISTRY",

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TY - JOUR

T1 - The N,N '-bis(trimethylsilyl)pentafluorobenzamidinate ligand

T2 - enhanced ethene oligomerisation with a neutral V(III) bis(benzamidinate) alkyl catalyst

AU - Brussee, Edward A.C.

AU - Meetsma, Auke

AU - Hessen, Bart

AU - Teuben, Jan H.

N1 - Relation: http://www.rug.nl/scheikunde/ date_submitted:2005 Rights: University of Groningen. Stratingh Institute

PY - 2000

Y1 - 2000

N2 - The pentafluorobenzamidinate ligand [C6F5C(NSiMe3)2]- is reported, together with its bis(benzamidinate) vanadium(III) methyl derivative; the latter is considerably more active in catalytic ethene oligomerisation than its non-fluorinated analogue.

AB - The pentafluorobenzamidinate ligand [C6F5C(NSiMe3)2]- is reported, together with its bis(benzamidinate) vanadium(III) methyl derivative; the latter is considerably more active in catalytic ethene oligomerisation than its non-fluorinated analogue.

KW - COORDINATION CHEMISTRY

KW - POLYMERIZATION

KW - COMPLEXES

KW - ZIRCONIUM

KW - TITANIUM

U2 - 10.1039/b000397m

DO - 10.1039/b000397m

M3 - Article

SN - 1359-7345

VL - 591

SP - 497

EP - 498

JO - Chemical Communications (Cambridge, United Kingdom)

JF - Chemical Communications (Cambridge, United Kingdom)

IS - 6

ER -

The N,N '-bis(trimethylsilyl)pentafluorobenzamidinate ligand: enhanced ethene oligomerisation with a neutral V(III) bis(benzamidinate) alkyl catalyst

Abstract

Keywords

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Datasets

CCDC 138322: Experimental Crystal Structure Determination

CCDC 138323: Experimental Crystal Structure Determination

Cite this