The N,N '-bis(trimethylsilyl)pentafluorobenzamidinate ligand: enhanced ethene oligomerisation with a neutral V(III) bis(benzamidinate) alkyl catalyst

Edward A.C. Brussee, Auke Meetsma, Bart Hessen, Jan H. Teuben

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75 Citations (Scopus)

Abstract

The pentafluorobenzamidinate ligand [C6F5C(NSiMe3)2]- is reported, together with its bis(benzamidinate) vanadium(III) methyl derivative; the latter is considerably more active in catalytic ethene oligomerisation than its non-fluorinated analogue.
Original languageEnglish
Pages (from-to)497-498
Number of pages2
JournalChemical Communications
Volume591
Issue number6
DOIs
Publication statusPublished - 2000

Keywords

  • COORDINATION CHEMISTRY
  • POLYMERIZATION
  • COMPLEXES
  • ZIRCONIUM
  • TITANIUM

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