The role of emissive charge transfer states in two polymer-fullerene organic photovoltaic blends: Tuning charge photogeneration through the use of processing additives

Tracey M. Clarke*, Jeff Peet, Christoph Lungenschmied, Nicolas Drolet, Xinhui Lu, Benjamin M. Ocko, Attila J. Mozer, Maria Antonietta Loi

*Corresponding author for this work

Research output: Contribution to journalArticleAcademicpeer-review

10 Citations (Scopus)

Abstract

The role of charge transfer (CT) states in organic photovoltaic systems has been debated in the recent literature. In this paper the device performances of two structurally analogous polymers PDTSiTTz (also known as KP115) and PCPDTTTz blended with PCBM are investigated, focusing on the effect the processing additive diiodooctane (DIO) has on morphology, charge photogeneration, and, in particular, the CT state characteristics. While DIO has a considerable beneficial effect for PCPDTTTz: PCBM photovoltaic devices, negligible effects are observed for PDTSiTTz: PCBM devices. An emissive CT state able to be quenched by DIO was observed for PCPDTTTz: PCBM, despite relatively small morphological changes. This is only the second instance of CT state quenching by a processing additive to be reported. Formation of an emissive CT state is therefore a loss pathway for PCPDTTTz: PCBM, which can be alleviated through the use of DIO to increase the proportion of CT states that dissociate into free charges. Conversely, the CT state of PDTSiTTZ:PCBM is weak and short-lived, with the DIO having little effect. The CT state dissociates more efficiently for this higher crystallinity system, leading to less evidence of emissive CT state recombination, and high charge photogeneration yields and device efficiencies.

Original languageEnglish
Pages (from-to)12583-12593
Number of pages11
JournalJournal of Materials Chemistry A
Volume2
Issue number31
DOIs
Publication statusPublished - 2014

Keywords

  • TRANSIENT ABSORPTION-SPECTROSCOPY
  • REDUCED BIMOLECULAR RECOMBINATION
  • HETEROJUNCTION SOLAR-CELLS
  • HOT EXCITON DISSOCIATION
  • BULK-HETEROJUNCTIONS
  • POLYTHIOPHENE FILMS
  • SOLVENT ADDITIVES
  • GENERATION
  • MORPHOLOGY
  • CARRIER

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