The Spectrum of the Molecular Eigenstates of Pyrazine and the Reconstruction of Decays of Rotational States of the 1B3u (0-0) Transition of Pyrazine

Barend J. van der Meer, Harry Th. Jonkman, Jan Kommandeur

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    Abstract

    The spectrum of the molecular eigenstates (ME) belonging to the various rotational members of the 1B3u (0-0) transition of pyrazine was measured with a very narrow band laser in a molecular beam with a Doppler width of 30 MHz. It is shown that, when the ME’s belonging to a single rotational state are Fourier-transformed, the beating decays of these states are obtained. A problem is constituted by the lack of a fast component in these reconstructions, while it is observed in experiments on higher J-states.
    Original languageEnglish
    Number of pages13
    JournalLaser Chemistry
    Volume2
    Issue number3
    DOIs
    Publication statusPublished - 1983

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