The Synthesis of (+)-Hedycaryol, Starting from Natural (–)-Guaiol

Adriaan J. Minnaard; Joannes B.P.A. Wijnberg; Aede de Groot

doi:10.1016/S0040-4020(01)85014-6

The Synthesis of (+)-Hedycaryol, Starting from Natural (–)-Guaiol

Adriaan J. Minnaard
, Joannes B.P.A. Wijnberg
, Aede de Groot

Research output: Contribution to journal › Article › Academic › peer-review

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Abstract

Starting from the readily available (–)-guaiol the germacrane sesquiterpene (+)-hedycaryol can be synthesized in a 7 steps reaction sequence in an overall yield of 16%. Additionally, (+)-γ-eudesmol has been synthesized, also starting from (–)-guaiol.

Original language	English
Pages (from-to)	4755-4764
Number of pages	10
Journal	Tetrahedron
Volume	50
Issue number	16
DOIs	https://doi.org/10.1016/S0040-4020(01)85014-6
Publication status	Published - Apr-1994
Externally published	Yes

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The Synthesis of (+)-Hedycaryol, Starting from Natural (–)-Guaio
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title = "The Synthesis of (+)-Hedycaryol, Starting from Natural (–)-Guaiol",

abstract = "Starting from the readily available (–)-guaiol the germacrane sesquiterpene (+)-hedycaryol can be synthesized in a 7 steps reaction sequence in an overall yield of 16\%. Additionally, (+)-γ-eudesmol has been synthesized, also starting from (–)-guaiol.",

author = "Minnaard, \{Adriaan J.\} and Wijnberg, \{Joannes B.P.A.\} and Groot, \{Aede de\}",

note = "Relation: http://www.rug.nl/scheikunde/ date\_submitted:2005 Rights: University of Groningen. Stratingh Institute",

year = "1994",

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AU - Wijnberg, Joannes B.P.A.

AU - Groot, Aede de

N1 - Relation: http://www.rug.nl/scheikunde/ date_submitted:2005 Rights: University of Groningen. Stratingh Institute

PY - 1994/4

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N2 - Starting from the readily available (–)-guaiol the germacrane sesquiterpene (+)-hedycaryol can be synthesized in a 7 steps reaction sequence in an overall yield of 16%. Additionally, (+)-γ-eudesmol has been synthesized, also starting from (–)-guaiol.

AB - Starting from the readily available (–)-guaiol the germacrane sesquiterpene (+)-hedycaryol can be synthesized in a 7 steps reaction sequence in an overall yield of 16%. Additionally, (+)-γ-eudesmol has been synthesized, also starting from (–)-guaiol.

U2 - 10.1016/S0040-4020(01)85014-6

DO - 10.1016/S0040-4020(01)85014-6

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SP - 4755

EP - 4764

JO - Tetrahedron

JF - Tetrahedron

IS - 16

ER -

The Synthesis of (+)-Hedycaryol, Starting from Natural (–)-Guaiol

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