Time correlation function and finite field approaches to the calculation of the fifth order Raman response in liquid xenon

Russell DeVane*, Brian Space, Thomas L. C. Jansen, T. Keyes

*Corresponding author for this work

Research output: Contribution to journalArticleAcademicpeer-review

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Abstract

The fifth order, two-dimensional Raman response in liquid xenon is calculated via a time correlation function (TCF) theory and the numerically exact finite field method. Both employ classical molecular dynamics simulations. The results are shown to be in excellent agreement, suggesting the efficacy of the TCF approach, in which the response function is written approximately in terms of a single classical multitime TCF. (c) 2006 American Institute of Physics.

Original languageEnglish
Article number234501
Pages (from-to)234501-1 - 234501-5
Number of pages5
JournalJournal of Chemical Physics
Volume125
Issue number23
DOIs
Publication statusPublished - 21-Dec-2006

Keywords

  • HETERODYNE-DETECTION
  • ATOMIC LIQUID
  • POLARIZATION SELECTIVITY
  • DIPOLE INTERACTION
  • MOLECULAR-ORIGINS
  • CS2
  • SPECTROSCOPY
  • SPECTRUM
  • POLARIZABILITIES
  • TEMPERATURE

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