Towards internal structuring of electrospun fibers by hierarchical self-assembly of polymeric comb-shaped supramolecules

T Ruotsalainen; J Turku; P Heikkila; J Ruokolainen; A Nykanen; T Laitinen; M Torkkeli; R Serimaa; G ten Brinke; A Harlin; O Ikkala; Pirjo Heikkilä; Antti Nykänen

doi:10.1002/adma.200401530

Towards internal structuring of electrospun fibers by hierarchical self-assembly of polymeric comb-shaped supramolecules

T Ruotsalainen
, J Turku
, P Heikkila
, J Ruokolainen
, A Nykanen
, T Laitinen
, M Torkkeli
, R Serimaa
, G ten Brinke
, A Harlin^*
, O Ikkala
, Pirjo Heikkilä
, Antti Nykänen

^*Corresponding author for this work

Research output: Contribution to journal › Article › Academic › peer-review

74 Citations (Scopus)

543 Downloads (Pure)

Abstract

Polystyrene-block-poly(4-vinylpyridine) with nominally one pentadecylphenol molecule hydrogen-bonded to each pyridine group has been electrospun, leading to fibers with a hierarchical, structure-within-structure morphology (see Figure). An internal structure on the nanometer length scale exists within a structure on the tens-of-manometers length scale. Internal porosity can be obtained by selective removal of the amphiphile.

Original language	English
Pages (from-to)	1048-+
Number of pages	6
Journal	Advanced materials
Volume	17
Issue number	8
DOIs	https://doi.org/10.1002/adma.200401530
Publication status	Published - 18-Apr-2005

Keywords

BLOCK-COPOLYMERS
MESOPOROUS MATERIALS
SURFACE-MORPHOLOGY
SOFT MATERIALS
LENGTH SCALES
FILMS
TEMPLATE
COLLOIDS

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Ruotsalainen, T., Turku, J., Heikkila, P., Ruokolainen, J., Nykanen, A., Laitinen, T., Torkkeli, M., Serimaa, R., ten Brinke, G., Harlin, A., Ikkala, O., Heikkilä, P., & Nykänen, A. (2005). Towards internal structuring of electrospun fibers by hierarchical self-assembly of polymeric comb-shaped supramolecules. Advanced materials, 17(8), 1048-+. https://doi.org/10.1002/adma.200401530

@article{04c86f47ad6d456ba3947e0c63aa43be,

title = "Towards internal structuring of electrospun fibers by hierarchical self-assembly of polymeric comb-shaped supramolecules",

abstract = "Polystyrene-block-poly(4-vinylpyridine) with nominally one pentadecylphenol molecule hydrogen-bonded to each pyridine group has been electrospun, leading to fibers with a hierarchical, structure-within-structure morphology (see Figure). An internal structure on the nanometer length scale exists within a structure on the tens-of-manometers length scale. Internal porosity can be obtained by selective removal of the amphiphile.",

keywords = "BLOCK-COPOLYMERS, MESOPOROUS MATERIALS, SURFACE-MORPHOLOGY, SOFT MATERIALS, LENGTH SCALES, FILMS, TEMPLATE, COLLOIDS",

author = "T Ruotsalainen and J Turku and P Heikkila and J Ruokolainen and A Nykanen and T Laitinen and M Torkkeli and R Serimaa and \{ten Brinke\}, G and A Harlin and O Ikkala and Pirjo Heikkil{\"a} and Antti Nyk{\"a}nen",

year = "2005",

month = apr,

day = "18",

doi = "10.1002/adma.200401530",

language = "English",

volume = "17",

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Ruotsalainen, T, Turku, J, Heikkila, P, Ruokolainen, J, Nykanen, A, Laitinen, T, Torkkeli, M, Serimaa, R, ten Brinke, G, Harlin, A, Ikkala, O, Heikkilä, P & Nykänen, A 2005, 'Towards internal structuring of electrospun fibers by hierarchical self-assembly of polymeric comb-shaped supramolecules', Advanced materials, vol. 17, no. 8, pp. 1048-+. https://doi.org/10.1002/adma.200401530

TY - JOUR

T1 - Towards internal structuring of electrospun fibers by hierarchical self-assembly of polymeric comb-shaped supramolecules

AU - Ruotsalainen, T

AU - Turku, J

AU - Heikkila, P

AU - Ruokolainen, J

AU - Nykanen, A

AU - Laitinen, T

AU - Torkkeli, M

AU - Serimaa, R

AU - ten Brinke, G

AU - Harlin, A

AU - Ikkala, O

AU - Heikkilä, Pirjo

AU - Nykänen, Antti

PY - 2005/4/18

Y1 - 2005/4/18

N2 - Polystyrene-block-poly(4-vinylpyridine) with nominally one pentadecylphenol molecule hydrogen-bonded to each pyridine group has been electrospun, leading to fibers with a hierarchical, structure-within-structure morphology (see Figure). An internal structure on the nanometer length scale exists within a structure on the tens-of-manometers length scale. Internal porosity can be obtained by selective removal of the amphiphile.

AB - Polystyrene-block-poly(4-vinylpyridine) with nominally one pentadecylphenol molecule hydrogen-bonded to each pyridine group has been electrospun, leading to fibers with a hierarchical, structure-within-structure morphology (see Figure). An internal structure on the nanometer length scale exists within a structure on the tens-of-manometers length scale. Internal porosity can be obtained by selective removal of the amphiphile.

KW - BLOCK-COPOLYMERS

KW - MESOPOROUS MATERIALS

KW - SURFACE-MORPHOLOGY

KW - SOFT MATERIALS

KW - LENGTH SCALES

KW - FILMS

KW - TEMPLATE

KW - COLLOIDS

U2 - 10.1002/adma.200401530

DO - 10.1002/adma.200401530

M3 - Article

SN - 0935-9648

VL - 17

SP - 1048-+

JO - Advanced materials

JF - Advanced materials

IS - 8

ER -

Towards internal structuring of electrospun fibers by hierarchical self-assembly of polymeric comb-shaped supramolecules

Abstract

Keywords

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