Zintl Ions as Structural Units in Liquid Alloys

W van der Lugt

doi:10.1088/0031-8949/1991/T39/059

Zintl Ions as Structural Units in Liquid Alloys

W van der Lugt^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › Academic › peer-review

38 Citations (Scopus)

Abstract

Anion clustering according to a rule discovered by E. Zintl may occur in ionic alloys. The chemical bonds between the anions are predominantly covalent. The drastic consequences of this effect for the electronic and structural properties of liquid ionic alloys are demonstrated for alloys of alkali metals with Pb, Sn, Bi, Tl and In.

Original language	English
Pages (from-to)	372-377
Number of pages	6
Journal	Physica Scripta
Volume	T39
DOIs	https://doi.org/10.1088/0031-8949/1991/T39/059
Publication status	Published - 1991
Event	11TH GENERAL CONF OF THE CONDENSED MATTER DIVISION OF THE EUROPEAN PHYSICAL SOC - Duration: 8-Apr-1991 → 11-Apr-1991

Keywords

ELECTROMOTIVE-FORCE MEASUREMENTS
SHORT-RANGE ORDER
LI-PB ALLOYS
ELECTRONIC-STRUCTURE
THERMODYNAMIC PROPERTIES
ALKALI-LEAD
BI ALLOYS
MOLECULAR-DYNAMICS
HEAT-CAPACITY
BETA-NASN

Access to Document

10.1088/0031-8949/1991/T39/059

Cite this

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title = "Zintl Ions as Structural Units in Liquid Alloys",

abstract = "Anion clustering according to a rule discovered by E. Zintl may occur in ionic alloys. The chemical bonds between the anions are predominantly covalent. The drastic consequences of this effect for the electronic and structural properties of liquid ionic alloys are demonstrated for alloys of alkali metals with Pb, Sn, Bi, Tl and In.",

keywords = "ELECTROMOTIVE-FORCE MEASUREMENTS, SHORT-RANGE ORDER, LI-PB ALLOYS, ELECTRONIC-STRUCTURE, THERMODYNAMIC PROPERTIES, ALKALI-LEAD, BI ALLOYS, MOLECULAR-DYNAMICS, HEAT-CAPACITY, BETA-NASN",

author = "{van der Lugt}, W",

year = "1991",

doi = "10.1088/0031-8949/1991/T39/059",

language = "English",

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pages = "372--377",

journal = "Physica Scripta",

issn = "0031-8949",

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note = "11TH GENERAL CONF OF THE CONDENSED MATTER DIVISION OF THE EUROPEAN PHYSICAL SOC ; Conference date: 08-04-1991 Through 11-04-1991",

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TY - JOUR

T1 - Zintl Ions as Structural Units in Liquid Alloys

AU - van der Lugt, W

PY - 1991

Y1 - 1991

N2 - Anion clustering according to a rule discovered by E. Zintl may occur in ionic alloys. The chemical bonds between the anions are predominantly covalent. The drastic consequences of this effect for the electronic and structural properties of liquid ionic alloys are demonstrated for alloys of alkali metals with Pb, Sn, Bi, Tl and In.

AB - Anion clustering according to a rule discovered by E. Zintl may occur in ionic alloys. The chemical bonds between the anions are predominantly covalent. The drastic consequences of this effect for the electronic and structural properties of liquid ionic alloys are demonstrated for alloys of alkali metals with Pb, Sn, Bi, Tl and In.

KW - ELECTROMOTIVE-FORCE MEASUREMENTS

KW - SHORT-RANGE ORDER

KW - LI-PB ALLOYS

KW - ELECTRONIC-STRUCTURE

KW - THERMODYNAMIC PROPERTIES

KW - ALKALI-LEAD

KW - BI ALLOYS

KW - MOLECULAR-DYNAMICS

KW - HEAT-CAPACITY

KW - BETA-NASN

U2 - 10.1088/0031-8949/1991/T39/059

DO - 10.1088/0031-8949/1991/T39/059

M3 - Article

VL - T39

SP - 372

EP - 377

JO - Physica Scripta

JF - Physica Scripta

SN - 0031-8949

T2 - 11TH GENERAL CONF OF THE CONDENSED MATTER DIVISION OF THE EUROPEAN PHYSICAL SOC

Y2 - 8 April 1991 through 11 April 1991

ER -