A Chemically Driven Rotary Molecular Motor Based on Reversible Lactone Formation with Perfect Unidirectionality

Yu Zhang; Zhe Chang; Heng Zhao; Stefano Crespi; Ben L. Feringa; Depeng Zhao

doi:10.1016/j.chempr.2020.07.025

A Chemically Driven Rotary Molecular Motor Based on Reversible Lactone Formation with Perfect Unidirectionality

Yu Zhang, Zhe Chang, Heng Zhao, Stefano Crespi, Ben L. Feringa^*, Depeng Zhao

^*Corresponding author voor dit werk

Synthetische Organische Chemie

Onderzoeksoutput: Article › Academic › peer review

36 Citaten (Scopus)

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A chemically driven molecular motor has been designed, which proceeds through stepwise movements fueled by chemical energy and undergoes full 360° unidirectional rotation. A record, nearly 100% unidirectionality is realized during the whole rotary process.

Originele taal-2	English
Pagina's (van-tot)	2420-2429
Aantal pagina's	10
Tijdschrift	Chem
Volume	6
Nummer van het tijdschrift	9
DOI's	https://doi.org/10.1016/j.chempr.2020.07.025
Status	Published - 10-sep.-2020

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A Chemically Driven Rotary Molecular Motor Based on Reversible Lactone Formation with Perfect UnidirectionalityFinal publisher's version, 1,78 MBLicentie: Taverne

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CCDC 1914274: Experimental Crystal Structure Determination
Chang, Z. (Contributor), Zhao, D. (Contributor), Zhao, H. (Contributor), Zhang, Y. (Contributor), Crespi, S. (Contributor) & Feringa, B. L. (Contributor), Cambridge Crystallographic Data Centre, 1-jun.-2019
DOI: 10.5517/ccdc.csd.cc227ys2
Dataset
CCDC 1914279: Experimental Crystal Structure Determination
Zhang, Y. (Contributor), Zhao, D. (Contributor), Crespi, S. (Contributor), Zhao, H. (Contributor), Feringa, B. L. (Contributor) & Chang, Z. (Contributor), Cambridge Crystallographic Data Centre, 7-mei-2019
DOI: 10.5517/ccdc.csd.cc227yy7
Dataset
CCDC 1914275: Experimental Crystal Structure Determination
Zhang, Y. (Contributor), Chang, Z. (Contributor), Zhao, H. (Contributor), Zhao, D. (Contributor), Crespi, S. (Contributor) & Feringa, B. L. (Contributor), Cambridge Crystallographic Data Centre, 7-mei-2019
DOI: 10.5517/ccdc.csd.cc227yt3
Dataset

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@article{6558681d3a5940deaf1f397a2a2c954f,

title = "A Chemically Driven Rotary Molecular Motor Based on Reversible Lactone Formation with Perfect Unidirectionality",

abstract = "A chemically driven molecular motor has been designed, which proceeds through stepwise movements fueled by chemical energy and undergoes full 360° unidirectional rotation. A record, nearly 100\% unidirectionality is realized during the whole rotary process.",

keywords = "biaryl, chemical energy, chirality, dynamic covalent bond, isomerization, lactone, molecular motor, out-of-equilibrium, SDG9: Industry, innovation, and infrastructure, system chemistry, unidirectional rotation",

author = "Yu Zhang and Zhe Chang and Heng Zhao and Stefano Crespi and Feringa, \{Ben L.\} and Depeng Zhao",

note = "Funding Information: We are grateful for the support of this work by the National Natural Science Foundation of China ( 21801260 and 21971267 ), Guangdong Provincial Key Laboratory of Chiral Molecule and Drug Discovery ( 2019B030301005 ), the 1000-Talent Youth Program of China, and the program for Guangdong Introducing Innovative and Entrepreneurial Teams ( 2017ZT07C069 ). S.C. acknowledges financial support from the Horizon 2020 Framework Programme (Marie Sk{\l}odowska-Curie grant no. 838280 ). B.L.F. acknowledges financial support from the Netherlands Ministry of Education, Culture, and Science (Gravitation Program no. 024.001.035 ). Publisher Copyright: {\textcopyright} 2020 Elsevier Inc. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.",

year = "2020",

month = sep,

day = "10",

doi = "10.1016/j.chempr.2020.07.025",

language = "English",

volume = "6",

pages = "2420--2429",

journal = "Chem",

issn = "2451-9308",

publisher = "Cell Press",

number = "9",

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T1 - A Chemically Driven Rotary Molecular Motor Based on Reversible Lactone Formation with Perfect Unidirectionality

AU - Zhang, Yu

AU - Chang, Zhe

AU - Zhao, Heng

AU - Crespi, Stefano

AU - Feringa, Ben L.

AU - Zhao, Depeng

N1 - Funding Information: We are grateful for the support of this work by the National Natural Science Foundation of China ( 21801260 and 21971267 ), Guangdong Provincial Key Laboratory of Chiral Molecule and Drug Discovery ( 2019B030301005 ), the 1000-Talent Youth Program of China, and the program for Guangdong Introducing Innovative and Entrepreneurial Teams ( 2017ZT07C069 ). S.C. acknowledges financial support from the Horizon 2020 Framework Programme (Marie Skłodowska-Curie grant no. 838280 ). B.L.F. acknowledges financial support from the Netherlands Ministry of Education, Culture, and Science (Gravitation Program no. 024.001.035 ). Publisher Copyright: © 2020 Elsevier Inc. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.

PY - 2020/9/10

Y1 - 2020/9/10

N2 - A chemically driven molecular motor has been designed, which proceeds through stepwise movements fueled by chemical energy and undergoes full 360° unidirectional rotation. A record, nearly 100% unidirectionality is realized during the whole rotary process.

AB - A chemically driven molecular motor has been designed, which proceeds through stepwise movements fueled by chemical energy and undergoes full 360° unidirectional rotation. A record, nearly 100% unidirectionality is realized during the whole rotary process.

KW - biaryl

KW - chemical energy

KW - chirality

KW - dynamic covalent bond

KW - isomerization

KW - lactone

KW - molecular motor

KW - out-of-equilibrium

KW - SDG9: Industry, innovation, and infrastructure

KW - system chemistry

KW - unidirectional rotation

UR - http://www.scopus.com/inward/record.url?scp=85090007837&partnerID=8YFLogxK

U2 - 10.1016/j.chempr.2020.07.025

DO - 10.1016/j.chempr.2020.07.025

M3 - Article

AN - SCOPUS:85090007837

SN - 2451-9308

VL - 6

SP - 2420

EP - 2429

JO - Chem

JF - Chem

IS - 9

ER -

A Chemically Driven Rotary Molecular Motor Based on Reversible Lactone Formation with Perfect Unidirectionality

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CCDC 1914274: Experimental Crystal Structure Determination

CCDC 1914279: Experimental Crystal Structure Determination

CCDC 1914275: Experimental Crystal Structure Determination

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