A nonheme peroxo-diiron(iii) complex exhibiting both nucleophilic and electrophilic oxidation of organic substrates

Patrik Torok, Duenpen Unjaroen, Flora Viktoria Csendes, Michel Giorgi, Wesley R. Browne*, Jozsef Kaizer*

*Bijbehorende auteur voor dit werk

OnderzoeksoutputAcademicpeer review

1 Citaat (Scopus)
7 Downloads (Pure)

Samenvatting

The complex [FeIII2(mu-O-2)(L-3)(4)(S)(2)](4+) (L-3 = 2-(4-thiazolyl)benzimidazole, S = solvent) forms upon reaction of [Fe-II(L-3)(2)] with H2O2 and is a functional model of peroxo-diiron intermediates invoked during the catalytic cycle of oxidoreductases. The spectroscopic properties of the complex are in line with those of complexes formed with N-donor ligands. [FeIII2(mu-O-2)(L-3)(4)(S)(2)](4+) shows both nucleophilic (aldehydes) and electrophilic (phenol, N,N-dimethylanilines) oxidative reactivity and unusually also electron transfer oxidation.

Originele taal-2English
Pagina's (van-tot)7181–7185
Aantal pagina's5
TijdschriftDalton Transactions
Volume50
Vroegere onlinedatum17-mei-2021
DOI's
StatusPublished - mei-2021

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