Acrylamide Homopolymers and Acrylamide-N-Isopropylacrylamide Block Copolymers by Atomic Transfer Radical Polymerization in Water

D. A. Z. Wever; P. Raffa; F. Picchioni; A. A. Broekhuis

doi:10.1021/ma3006125

Acrylamide Homopolymers and Acrylamide-N-Isopropylacrylamide Block Copolymers by Atomic Transfer Radical Polymerization in Water

D. A. Z. Wever, P. Raffa, F. Picchioni, A. A. Broekhuis^*

^*Bijbehorende auteur voor dit werk

Onderzoeksoutput › Academic › peer review

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Atomic transfer radical polymerization (ATRP) of acrylamide has been accomplished in aqueous media at room temperature. By using methyl 2-chloropropionate (MeClPr) as the initiator and tris[2-(dimethylamino)ethyl]-amine (Me6TREN)/copper halogenide (CuX) as the catalyst system, different linear polyacrylamides with apparent molecular weights up to >150 000 g/mol were synthesized with dispersities as low as 1.39. The molecular weights agreed well with the theoretical ones at relatively low-medium monomer/initiator ratios (

Originele taal-2	English
Pagina's (van-tot)	4040-4045
Aantal pagina's	6
Tijdschrift	Macromolecules
Volume	45
Nummer van het tijdschrift	10
DOI's	https://doi.org/10.1021/ma3006125
Status	Published - 22-mei-2012

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title = "Acrylamide Homopolymers and Acrylamide-N-Isopropylacrylamide Block Copolymers by Atomic Transfer Radical Polymerization in Water",

abstract = "Atomic transfer radical polymerization (ATRP) of acrylamide has been accomplished in aqueous media at room temperature. By using methyl 2-chloropropionate (MeClPr) as the initiator and tris[2-(dimethylamino)ethyl]-amine (Me6TREN)/copper halogenide (CuX) as the catalyst system, different linear polyacrylamides with apparent molecular weights up to >150 000 g/mol were synthesized with dispersities as low as 1.39. The molecular weights agreed well with the theoretical ones at relatively low-medium monomer/initiator ratios (",

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author = "Wever, {D. A. Z.} and P. Raffa and F. Picchioni and Broekhuis, {A. A.}",

year = "2012",

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T1 - Acrylamide Homopolymers and Acrylamide-N-Isopropylacrylamide Block Copolymers by Atomic Transfer Radical Polymerization in Water

AU - Wever, D. A. Z.

AU - Raffa, P.

AU - Picchioni, F.

AU - Broekhuis, A. A.

PY - 2012/5/22

Y1 - 2012/5/22

N2 - Atomic transfer radical polymerization (ATRP) of acrylamide has been accomplished in aqueous media at room temperature. By using methyl 2-chloropropionate (MeClPr) as the initiator and tris[2-(dimethylamino)ethyl]-amine (Me6TREN)/copper halogenide (CuX) as the catalyst system, different linear polyacrylamides with apparent molecular weights up to >150 000 g/mol were synthesized with dispersities as low as 1.39. The molecular weights agreed well with the theoretical ones at relatively low-medium monomer/initiator ratios (

AB - Atomic transfer radical polymerization (ATRP) of acrylamide has been accomplished in aqueous media at room temperature. By using methyl 2-chloropropionate (MeClPr) as the initiator and tris[2-(dimethylamino)ethyl]-amine (Me6TREN)/copper halogenide (CuX) as the catalyst system, different linear polyacrylamides with apparent molecular weights up to >150 000 g/mol were synthesized with dispersities as low as 1.39. The molecular weights agreed well with the theoretical ones at relatively low-medium monomer/initiator ratios (

KW - AMBIENT-TEMPERATURE

KW - AQUEOUS-MEDIA

KW - ATRP

KW - N,N-DIMETHYLACRYLAMIDE

KW - METHACRYLATE

KW - POLYMERS

KW - (METH)ACRYLAMIDES

KW - CONSTANTS

U2 - 10.1021/ma3006125

DO - 10.1021/ma3006125

M3 - Article

SN - 0024-9297

VL - 45

SP - 4040

EP - 4045

JO - Macromolecules

JF - Macromolecules

IS - 10

ER -