Catalytic enantioselective synthesis of vicinal dialkyl arrays

Anthoni W. van Zijl, Wiktor Szymanski, Ferrnando Lopez, Adriaan J. Minnaard*, Ben L. Feringa

*Bijbehorende auteur voor dit werk

OnderzoeksoutputAcademicpeer review

49 Citaten (Scopus)
25 Downloads (Pure)

Samenvatting

With a consecutive "asymmetric allylic alkylation (AAA)/cross-metathesis (CM)/conjugate addition (CA)" protocol it is possible to synthesize either stereoisomer of compounds containing a vicinal dialkyl array with excellent stereoselectivity. The versatility of this protocol in natural product synthesis is demonstrated in the preparation of the ant pheromones faranal and lasiol.

Originele taal-2English
Pagina's (van-tot)6994-7002
Aantal pagina's9
TijdschriftJournal of Organic Chemistry
Volume73
Nummer van het tijdschrift18
DOI's
StatusPublished - 19-sep-2008

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