Cation-Modulated Rotary Speed in a Light-Driven Crown Ether Functionalized Molecular Motor

Ruth Dorel; Carla Miró; Yuchen Wei; Sander J. Wezenberg; Ben L. Feringa

doi:10.1021/acs.orglett.8b00969

Cation-Modulated Rotary Speed in a Light-Driven Crown Ether Functionalized Molecular Motor

Ruth Dorel, Carla Miró, Yuchen Wei, Sander J. Wezenberg, Ben L. Feringa^*

^*Corresponding author voor dit werk

Onderzoeksoutput: Article › Academic › peer review

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The design and synthesis of an overcrowded-alkene based molecular motor featuring a crown ether integrated in its stator structure has been accomplished. The photostationary state ratios and rotational speed of this motor can be modulated by cation coordination to the crown ether moiety, which can be reversed upon the addition of a competing chelating agent, thus achieving a dynamic control over the rotational behavior of the motor.

Originele taal-2	English
Pagina's (van-tot)	3715-3718
Aantal pagina's	4
Tijdschrift	Organic letters
Volume	20
Nummer van het tijdschrift	13
DOI's	https://doi.org/10.1021/acs.orglett.8b00969
Status	Published - 6-jul.-2018

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10.1021/acs.orglett.8b00969Licentie: CC BY-NC-ND

Cation-Modulated Rotary SpeedFinal publisher's version, 1,11 MBLicentie: CC BY-NC-ND

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title = "Cation-Modulated Rotary Speed in a Light-Driven Crown Ether Functionalized Molecular Motor",

abstract = "The design and synthesis of an overcrowded-alkene based molecular motor featuring a crown ether integrated in its stator structure has been accomplished. The photostationary state ratios and rotational speed of this motor can be modulated by cation coordination to the crown ether moiety, which can be reversed upon the addition of a competing chelating agent, thus achieving a dynamic control over the rotational behavior of the motor.",

keywords = "SINGLE STEREOGENIC CENTER, STRUCTURAL MODIFICATION, ROTATION, MOTION, ACCELERATION, SYSTEM, ROTOR",

author = "Ruth Dorel and Carla Mir{\'o} and Yuchen Wei and Wezenberg, \{Sander J.\} and Feringa, \{Ben L.\}",

year = "2018",

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doi = "10.1021/acs.orglett.8b00969",

language = "English",

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T1 - Cation-Modulated Rotary Speed in a Light-Driven Crown Ether Functionalized Molecular Motor

AU - Dorel, Ruth

AU - Miró, Carla

AU - Wei, Yuchen

AU - Wezenberg, Sander J.

AU - Feringa, Ben L.

PY - 2018/7/6

Y1 - 2018/7/6

N2 - The design and synthesis of an overcrowded-alkene based molecular motor featuring a crown ether integrated in its stator structure has been accomplished. The photostationary state ratios and rotational speed of this motor can be modulated by cation coordination to the crown ether moiety, which can be reversed upon the addition of a competing chelating agent, thus achieving a dynamic control over the rotational behavior of the motor.

AB - The design and synthesis of an overcrowded-alkene based molecular motor featuring a crown ether integrated in its stator structure has been accomplished. The photostationary state ratios and rotational speed of this motor can be modulated by cation coordination to the crown ether moiety, which can be reversed upon the addition of a competing chelating agent, thus achieving a dynamic control over the rotational behavior of the motor.

KW - SINGLE STEREOGENIC CENTER

KW - STRUCTURAL MODIFICATION

KW - ROTATION

KW - MOTION

KW - ACCELERATION

KW - SYSTEM

KW - ROTOR

U2 - 10.1021/acs.orglett.8b00969

DO - 10.1021/acs.orglett.8b00969

M3 - Article

SN - 1523-7060

VL - 20

SP - 3715

EP - 3718

JO - Organic letters

JF - Organic letters

IS - 13

ER -

Cation-Modulated Rotary Speed in a Light-Driven Crown Ether Functionalized Molecular Motor

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