Cerium Aryloxides as Precursors for Monopentamethylcyclopentadienyl Organocerium(III) Compounds; X-Ray Crystal Structure of (η5-Pentamethylcyclopentadienyl)bis(2,6-di-t-butylphenoxo)cerium

Hero J. Heeres, Auke Meetsma, Jan H. Teuben

    OnderzoeksoutputAcademic

    42 Citaten (Scopus)
    153 Downloads (Pure)

    Samenvatting

    Tris(2,6-di-t-butylphenoxo)cerium reacts with (C5Me5)Li in pentane to form (η5-C5Me5)bis(2,6-di-t-butylphenoxo)cerium, whose structure was established by X-ray crystallography and which, on subsequent reaction with LiCH(SiMe3)2, gives a novel mono(C5Me5)cerium-bisalkyl complex, (C5Me5)Ce[CH(SiMe3)2]2.
    Originele taal-2English
    Aantal pagina's2
    TijdschriftJournal of the Chemical Society%2C Chemical Communications
    Volume8
    Nummer van het tijdschrift14
    DOI's
    StatusPublished - 1988

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