Chiral-Selective Formation of 1D Polymers Based on Ullmann-Type Coupling: The Role of the Metallic Substrate

Tuan Anh Pham, Van Bay Tran, Manh-Thuong Nguyen, Meike Stöhr

OnderzoeksoutputAcademicpeer review

21 Citaten (Scopus)
297 Downloads (Pure)

Samenvatting

The chiral-selective formation of 1D polymers from a prochiral molecule, namely, 6,12-dibromochrysene in dependence of the type of metal surface is demonstrated by a combined scanning tunneling microscopy and density functional theory study. Deposition of the chosen molecule on Au(111) held at room temperature leads to the formation of a 2D porous molecular network. Upon annealing at 200 °C, an achiral covalently linked polymer is formed on Au(111). On the other hand, a chiral Cu-coordinated polymer is spontaneously formed upon deposition of the molecules on Cu(111) held at room temperature. Importantly, it is found that the chiral-selectivity determines the possibility of obtaining graphene nanoribbons (GNRs). On Au(111), upon annealing at 350 °C or higher cyclo-dehydrogenation occurs transforming the achiral polymer into a GNR. In contrast, the chiral coordination polymer on Cu(111) cannot be converted into a GNR.
Originele taal-2English
Artikelnummer1603675
TijdschriftSmall
Volume13
Nummer van het tijdschrift13
DOI's
StatusPublished - 4-apr-2017

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