Diels-Alder-Crosslinked Polymers Derived from Jatropha Oil

Muhammad Iqbal, Remco Arjen Knigge, Hero Jan Heeres, Antonius A. Broekhuis, Francesco Picchioni*

*Corresponding author voor dit werk

OnderzoeksoutputAcademicpeer review

7 Citaten (Scopus)
298 Downloads (Pure)

Samenvatting

Methyl oleate, methyl linoleate, and jatropha oil were fully epoxidized using in situ-generated performic acid. The epoxidized compounds were further reacted with furfurylamine in a solvent-free reaction to obtain furan-functionalized fatty esters which, then, functioned as oligomers for a network preparation. Thermoreversible crosslinking was obtained through a (retro) Diels-Alder reaction with bismaleimide, resulting in the formation of a brittle network for furan-functionalized methyl linoleate and jatropha oil. The furan-functionalized fatty esters were mixed with alternating (1,4)-polyketone reacted with furfurylamine (PK-Furan) for testing the mechanical and self-healing properties with DMTA and DSC, respectively. Full self-healing properties were found, and faster thermoreversibility kinetics were observed, compared to PK-Furan.

Originele taal-2English
Artikelnummer1177
Aantal pagina's17
TijdschriftPolymers
Volume10
Nummer van het tijdschrift10
DOI's
StatusPublished - okt.-2018

Vingerafdruk

Duik in de onderzoeksthema's van 'Diels-Alder-Crosslinked Polymers Derived from Jatropha Oil'. Samen vormen ze een unieke vingerafdruk.

Citeer dit