Samenvatting
The electronic structure of Ag2O has been investigated by photoelectron, Auger-electron, and bremsstrahlung isochromat spectroscopy. The experimental results are compared with model one-particle band-structure and two-particle cluster calculations. We extract values for the on-site Ag 4d and O 2p energies, the Ag 4d–O 2p transfer integrals, as well as the on-site Coulomb Ag 4d-4d and O 2p-2p interactions. A comparison with Cu2O and CuO is made, and the differences are discussed in view of high-Tc superconductivity and the instability of AgO.
Originele taal-2 | English |
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Pagina's (van-tot) | 3190-3199 |
Aantal pagina's | 10 |
Tijdschrift | Physical Review. B: Condensed Matter and Materials Physics |
Volume | 41 |
Nummer van het tijdschrift | 5 |
DOI's | |
Status | Published - 15-feb.-1990 |