Exchange-biased hybrid gamma-Fe2O3/NiO core-shell nanostructures: three-step synthesis, microstructure, and magnetic properties

Xue-Min He, Chuang-Wei Zhang, Fang-Fang Guo, Shi-Ming Yan, Yong-Tao Li*, Li-Qing Liu, Hong-Guang Zhang, You-Wei Du, Wei Zhong

*Bijbehorende auteur voor dit werk

OnderzoeksoutputAcademicpeer review

7 Citaten (Scopus)
2 Downloads (Pure)


A two-step solvothermal method combining a calcination process was conducted to synthesize gamma-Fe2O3/NiO core-shell nanostructures with controlled microstructure. The formation mechanism of this binary system has been discussed, and the influence of microstructures on magnetic properties has been analyzed in detail. Microstructural characterizations reveal that the NiO shells consisted of many irregular nanosheets with disordered orientations and monocrystalline structures, packed on the surface of the gamma-Fe2O3 microspheres. Both the grain size and NiO content of nanostructures increase with the increasing calcination temperature from 300 degrees C to 400 degrees C, accompanied by an enhancement of the compactness of NiO shells. Magnetic studies indicate that their magnetic properties are determined by four factors: the size effect, NiO phase content, interface microstructure, i.e. contact mode, area, roughness and compactness, and FM-AFM (where FM and AFM denote the ferromagnetic gamma-Fe2O3 and the antiferromagnetic NiO components, respectively) coupling effect. At 5 K, the gamma-Fe2O3/NiO core-shell nanostructures display certain exchange bias (H-E = 60 Oe) and enhanced coercivity (H-C = 213 Oe).

Originele taal-2English
Pagina's (van-tot)11967-11976
Aantal pagina's10
TijdschriftPhysical Chemistry Chemical Physics
Nummer van het tijdschrift22
StatusPublished - 14-jun-2019

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