From d- to l-Monosaccharide Derivatives via Photodecarboxylation-Alkylation

I. C. Steven Wan, Martin D. Witte*, Adriaan J. Minnaard

*Bijbehorende auteur voor dit werk

OnderzoeksoutputAcademicpeer review

40 Citaten (Scopus)
228 Downloads (Pure)

Samenvatting

Photodecarboxylation-alkylation of conformationally locked monosaccharides leads to inversion of stereochemistry at C5. This allows the synthesis of l-sugars from their readily available d-counterparts. Via this strategy, methyl l-guloside was synthesized from methyl d-mannoside in 21% yield over six steps.

Originele taal-2English
Pagina's (van-tot)7669-7673
Aantal pagina's5
TijdschriftOrganic letters
Volume21
Nummer van het tijdschrift18
DOI's
StatusPublished - 20-sep.-2019

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