Intermediate level structure, quantum beats, and nuclear spin effects in the electronic relaxation of the 1B3u (nπ*) state of pyrazine

Barend J.  van der Meer; Harry Th. Jonkman; Gerard M.  ter Horst; Jan Kommandeur

doi:10.1063/1.443185

Intermediate level structure, quantum beats, and nuclear spin effects in the electronic relaxation of the 1B3u (nπ*) state of pyrazine

Barend J. van der Meer, Harry Th. Jonkman, Gerard M. ter Horst, Jan Kommandeur

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The P(1) member of the rotational manifold of the 6a10 transition in the 1B3u (nπ) state of pyrazine shows intermediate level structure and quantum beats in its decay. The P(2) member already shows a fast component. The effect of nuclear spin on the relative magnitude of the fast component is shown by partial deuterium substitution.

Originele taal-2	English
Pagina's (van-tot)	2099-2100
Aantal pagina's	2
Tijdschrift	The Journal of Chemical Physics
Volume	76
Nummer van het tijdschrift	4
DOI's	https://doi.org/10.1063/1.443185
Status	Published - 1982

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10.1063/1.443185

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Citeer dit

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abstract = "The P(1) member of the rotational manifold of the 6a10 transition in the 1B3u (nπ) state of pyrazine shows intermediate level structure and quantum beats in its decay. The P(2) member already shows a fast component. The effect of nuclear spin on the relative magnitude of the fast component is shown by partial deuterium substitution.",

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AB - The P(1) member of the rotational manifold of the 6a10 transition in the 1B3u (nπ) state of pyrazine shows intermediate level structure and quantum beats in its decay. The P(2) member already shows a fast component. The effect of nuclear spin on the relative magnitude of the fast component is shown by partial deuterium substitution.

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