TY - CHAP
T1 - Iron(III) spin crossover compounds
AU - van Koningsbruggen, PJ
AU - Maeda, Y
AU - Oshio, H
N1 - Relation: http://www.rug.nl/scheikunde/
date_submitted:2006
Rights: University of Groningen. Stratingh Institute
PY - 2004
Y1 - 2004
N2 - In this chapter, selected results obtained so far on Fe(III) spin crossover compounds are summarized and discussed. Fe(III) spin transition materials of ligands containing chalcogen donor atoms are considered with emphasis on those of N,N-disubstituted-dithiocarbamates, N,N-disubstituted-XY-carbamates (XY=SO, SSe, SeSe), X-xanthates (X=O, S), monothio-beta-diketonates and X-semicarbazones (X=S, Se). In addition, attention is directed to Fe(III) spin crossover systems of multidentate Schiff base-type ligands. Examples of spin inter-conversion in Fe(III) compounds induced by light irradiation are given.
AB - In this chapter, selected results obtained so far on Fe(III) spin crossover compounds are summarized and discussed. Fe(III) spin transition materials of ligands containing chalcogen donor atoms are considered with emphasis on those of N,N-disubstituted-dithiocarbamates, N,N-disubstituted-XY-carbamates (XY=SO, SSe, SeSe), X-xanthates (X=O, S), monothio-beta-diketonates and X-semicarbazones (X=S, Se). In addition, attention is directed to Fe(III) spin crossover systems of multidentate Schiff base-type ligands. Examples of spin inter-conversion in Fe(III) compounds induced by light irradiation are given.
KW - spin crossover
KW - Fe(III)
KW - dithiocarbamate
KW - thiosemicarbazone
KW - Schiff base
KW - QUADRIDENTATE SCHIFF-BASES
KW - TRANSITION-METAL COMPLEXES
KW - ELECTRON-PARAMAGNETIC-RES
KW - RAY CRYSTAL-STRUCTURE
KW - SOLVATE SERIES <FE(3-OET-SALAPA)2>(CLO4).S
KW - DEPENDENT MAGNETIC-BEHAVIOR
KW - STATE RELAXATION DYNAMICS
KW - ASYMMETRIC LIGAND FIELDS
KW - LARGE THERMAL HYSTERESIS
KW - MONOTHIO-BETA-DIKETONES
U2 - 10.1007/b95409
DO - 10.1007/b95409
M3 - Chapter
T3 - TOPICS IN CURRENT CHEMISTRY
SP - 259
EP - 324
BT - SPIN CROSSOVER IN TRANSITION METAL COMPOUNDS I
PB - University of Groningen, Stratingh Institute for Chemistry
CY - BERLIN
ER -