Long-range exciton transport in brightly fluorescent furan/phenylene co-oligomer crystals

Artur A. Mannanov, Maxim S. Kazantsev, Anatoly D. Kuimov, Vladislav G. Konstantinov, Dmitry I. Dominskiy, Vasiliy A. Trukhanov, Daniil S. Anisimov, Nikita V. Gultikov, Vladimir V. Bruevich, Igor P. Koskin, Alina A. Sonina, Tatyana V. Rybalova, Inna K. Shundrina, Evgeny A. Mostovich, Dmitry Yu. Paraschuk, Maxim S. Pshenichnikov

OnderzoeksoutputAcademicpeer review

9 Citaten (Scopus)


The design of light-emitting crystalline organic semiconductors for optoelectronic applications requires a thorough understanding of the singlet exciton transport process. In this study, we show that the singlet exciton diffusion length in a promising semiconductor crystal based on furan/phenylene co-oligomers is 24 nm. To achieve this, we employed the photoluminescence quenching technique using a specially synthesized quencher, which is a long furan/phenylene co-oligomer that was facilely implanted into the host crystal lattice. Extensive Monte-Carlo simulations, exciton-exciton annihilation experiments and numerical modelling fully supported our findings. We further demonstrated the high potential of the furan/phenylene co-oligomer crystals for light-emitting applications by fabricating solution-processed organic light emitting transistors.

Originele taal-2English
Pagina's (van-tot)60-68
Aantal pagina's9
TijdschriftJournal of Materials Chemistry C
Nummer van het tijdschrift1
StatusPublished - 7-jan-2019

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