Metal-ion-induced shape switching: Stereoselective formation of a dinuclear Hg(II) double helicate from a hydrazonobis(acylhydrazone) ligand

Gael Schaeffer, Jack M. Harrowfield, Jean-Marie Lehn, Anna K. H. Hirsch*

*Bijbehorende auteur voor dit werk

OnderzoeksoutputAcademicpeer review

2 Citaten (Scopus)

Samenvatting

The unsymmetrical hydrazonobis(acylhydrazone) ligand L exists in solution as a mixture of isomers but complexes to Hg(II) with a major conformational change, affording a mixture of parallel and antiparallel binuclear double helicates. On crystallisation of the triflate salt, however, the antiparallel strand isomer is selected presumably due to the optimisation of several weak interactions. (c) 2012 Elsevier Ltd. All rights reserved.

Originele taal-2English
Pagina's (van-tot)40-43
Aantal pagina's4
TijdschriftPolyhedron
Volume41
Nummer van het tijdschrift1
DOI's
StatusPublished - 28-jun-2012

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