Monocyclopentadienyl Yttrium Chemistry: Incorporation of Alkoxides as Supporting Ligands and Synthesis of [Y(C5Me5)(OC6H3But2)(μ-H)]2

Colin J. Schaverien, John H.G. Frijns, Hero J. Heeres, J.R. van den Hende, Jan H. Teuben, Anthony L. Spek

OnderzoeksoutputAcademic

58 Citaten (Scopus)

Samenvatting

Reaction of the crystallographically characterised [Y(C5Me5)(OC6H3But2)2] 2 with LiCH(SiMe3)2 affords the mixed alkyl-alkoxide species [Y(C5Me5){CH(SiMe3)2}(OC6H3But2)] 3 which, on subsequent hydrogenation, gives the hydride bridged dimer [{Y(C5Me5)(OC6H3But2)(μ-H)}2] 4; 89Y NMR spectra of these, and related complexes, allows C5Me5, OC6H3But2 and CH(SiMe3)2 group contributions to be determined.
Originele taal-2English
Pagina's (van-tot)642-644
Aantal pagina's3
TijdschriftJournal of the Chemical Society, Chemical Communications
Volume414
Nummer van het tijdschrift9
DOI's
StatusPublished - 1991

Vingerafdruk

Duik in de onderzoeksthema's van 'Monocyclopentadienyl Yttrium Chemistry: Incorporation of Alkoxides as Supporting Ligands and Synthesis of [Y(C5Me5)(OC6H3But2)(μ-H)]2'. Samen vormen ze een unieke vingerafdruk.

Citeer dit