Omniconjugation

Marleen H. van der Veen, Harry T. Jonkman, Jan C. Hummelen

OnderzoeksoutputAcademicpeer review

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Samenvatting

Omniconjugation is introduced as a new architectural concept for the design of complex molecular structures that allows for the interconnection of many functional entities in a fully conjugated manner. So far, such π-conjugated topologies have never been explicitly recognized or investigated from this point of view. A topological design method has been developed by which a large number of realistic omniconjugated structures can be constructed. This new class of π-conjugated systems can be divided in two sub-classes that differ in their ‘switching’ behavior upon passage of solitons. Furthermore, we found that the principle of omniconjugation may give rise to a pronounced and, sometimes, unique π-electron delocalization of the frontier orbitals. These preliminary results indicate that omniconjugation could be applicable in several ways (as passive or active elements) in future nanoelectronic devices.
Originele taal-2English
TitelAmerican Institute of Physics Conference Proceedings (Proceedings 18th International Winter School on Electronic Properties of Novel Materials)
RedacteurenH Kuzmany, J Fink, M Mehring, S Roth
Plaats van productieMELVILLE
UitgeverijUniversity of Groningen, The Zernike Institute for Advanced Materials
Pagina's321 - 325
Aantal pagina's5
Volume723
ISBN van geprinte versie0-7354-0204-3
StatusPublished - 2004
Evenement18th International Winterschool/Euroconference on Electronic Properties of Novel Materials - , Austria
Duur: 6-mrt.-200413-jun.-2004

Publicatie series

NaamAIP CONFERENCE PROCEEDINGS
UitgeverijAMER INST PHYSICS
Volume723
ISSN van geprinte versie0094-243X

Other

Other18th International Winterschool/Euroconference on Electronic Properties of Novel Materials
Land/RegioAustria
Periode06/03/200413/06/2004

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