Properties of organic-inorganic hybrids: Chemistry, connectivity and confinement

Machteld Elizabeth Kamminga

Properties of organic-inorganic hybrids: Chemistry, connectivity and confinement

Vertaalde titel van de bijdrage: Eigenschappen van organisch-anorganische hybrides: Chemie, connectiviteit en insluiting

Machteld Elizabeth Kamminga

Solid State Materials for Electronics

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Dit proefschrift bevat onderzoek naar eigenschappen van organisch-anorganische hybrides. Organisch-anorganische hybrides zijn materialen die bestaan uit organische en anorganische componenten die samengevoegd zijn in een enkel materiaal. Organische en anorganische materialen hebben doorgaans verschillende eigenschappen: organische materialen hebben een flexibele structuur en zijn makkelijk te maken, terwijl anorganische materialen bekend staan om hun goede elektronische en magnetische eigenschappen en weerbaarheid tegen hoge temperaturen. Het combineren van beide componenten in een enkel hybride materiaal zorgt ervoor dat het materiaal eigenschappen van beide componenten bevat. Op deze manier kunnen unieke materialen gemaakt worden die het beste van beide werelden omarmen.

Ondanks dat verscheidene eigenschappen van organisch-anorganische hybrides zijn gerapporteerd is hun oorsprong niet altijd bekend. De mechanismen achter deze fysische fenomenen moeten soms nog ontdekt worden. Het is algemeen bekend dat de eigenschappen direct samenhangen met de structuur van het materiaal, maar er is nog genoeg te leren.

Het doel van dit onderzoek was om een beter fundamenteel begrip te krijgen van structuur-eigenschap relaties in organisch-anorganische hybrides. In andere worden, hoe verplaatsingen in de kristalstructuur fundamentele fysische eigenschappen, zoals optische, elektrische en magnetische eigenschappen, in organisch-anorganische hybrides kunnen beïnvloeden.

In dit onderzoek zijn zowel nieuwe als eerder gerapporteerde organisch-anorganische hybrides gesynthetiseerd, hun kristalstructuren bestudeerd en fundamentele fysische eigenschappen onderzocht. De bevindingen uit dit proefschrift voegen iets toe aan de bestaande kennis van de chemie, structuren en fysische eigenschappen van deze hybride materialen. Bovendien zijn een aantal hulpmiddelen gerapporteerd die men kan gebruiken om materialen te ontwerpen met specifieke eigenschappen voor gewenste toepassingen.

Vertaalde titel van de bijdrage	Eigenschappen van organisch-anorganische hybrides: Chemie, connectiviteit en insluiting
Originele taal-2	English
Kwalificatie	Doctor of Philosophy
Toekennende instantie	Rijksuniversiteit Groningen
Begeleider(s)/adviseur	Palstra, Thomas, Supervisor Loi, Maria, Supervisor Blake, Graeme, Co-supervisor
Datum van toekenning	22-jun.-2018
Plaats van publicatie	[Groningen]
Uitgever	Rijksuniversiteit Groningen
Gedrukte ISBN's	978-94-034-0702-9
Elektronische ISBN's	978-94-034-0701-2
Status	Published - 2018

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Title and contentsFinal publisher's version, 319 KB
Chapter 1Final publisher's version, 3,22 MB
Chapter 2Final publisher's version, 222 KB
Chapter 3Final publisher's version, 8,29 MB
Chapter 4Final publisher's version, 5,13 MB
Chapter 5Final publisher's version, 7,62 MB
Chapter 6Final publisher's version, 4,45 MB
Chapter 7Final publisher's version, 5,34 MB
Chapter 8Final publisher's version, 6,23 MB
Chapter 9Final publisher's version, 24,5 MB
SummaryFinal publisher's version, 70,6 KB
SamenvattingFinal publisher's version, 71 KB
AcknowledgementsFinal publisher's version, 74,9 KB
List of PublicationsFinal publisher's version, 70,5 KB
Structures Deposited in the Crystallographic DatabaseFinal publisher's version, 97 KB
Complete thesisFinal publisher's version, 64,3 MB
PropositionsFinal publisher's version, 44,3 KB

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title = "Properties of organic-inorganic hybrids: Chemistry, connectivity and confinement",

abstract = "This thesis investigated properties of organic-inorganic hybrids. Organic-inorganic hybrids are materials that consist of organic and inorganic components that are combined into a single compound. Organic and inorganic compounds generally have different properties: organic compounds have a flexible structure and are easy to make, while inorganic compounds are known for their excellent electronic and magnetic properties and resilience against high temperatures. Combining both components into a single hybrid compound gives rise to materials with properties that are associated with both components. Therefore, unique materials that are the best of both worlds can be created.While several properties of organic-inorganic hybrids have been reported, their origin is not always fully understood. The mechanisms behind the physical phenomena are sometimes yet to be found. It is commonly understood that the properties are directly related to the crystal structure, but there is still a lot to gain.The main goal of the research was to gain a better fundamental understanding of structure-property relations in organic-inorganic hybrids. In other words, how displacements in the crystal structure can change fundamental physical properties, including optical, electric and magnetic properties. In this work, both new and previously reported organic-inorganic hybrids are synthesized, their crystal structures are studied and fundamental physical properties are measured. The findings of this thesis add to the understanding of the chemistry, structures and physical properties of these hybrid materials. Furthermore, a few tools that are of use for direct tuning of certain physical properties of organic-inorganic hybrids for desired applications are reported.",

author = "Kamminga, {Machteld Elizabeth}",

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T2 - Chemistry, connectivity and confinement

AU - Kamminga, Machteld Elizabeth

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N2 - This thesis investigated properties of organic-inorganic hybrids. Organic-inorganic hybrids are materials that consist of organic and inorganic components that are combined into a single compound. Organic and inorganic compounds generally have different properties: organic compounds have a flexible structure and are easy to make, while inorganic compounds are known for their excellent electronic and magnetic properties and resilience against high temperatures. Combining both components into a single hybrid compound gives rise to materials with properties that are associated with both components. Therefore, unique materials that are the best of both worlds can be created.While several properties of organic-inorganic hybrids have been reported, their origin is not always fully understood. The mechanisms behind the physical phenomena are sometimes yet to be found. It is commonly understood that the properties are directly related to the crystal structure, but there is still a lot to gain.The main goal of the research was to gain a better fundamental understanding of structure-property relations in organic-inorganic hybrids. In other words, how displacements in the crystal structure can change fundamental physical properties, including optical, electric and magnetic properties. In this work, both new and previously reported organic-inorganic hybrids are synthesized, their crystal structures are studied and fundamental physical properties are measured. The findings of this thesis add to the understanding of the chemistry, structures and physical properties of these hybrid materials. Furthermore, a few tools that are of use for direct tuning of certain physical properties of organic-inorganic hybrids for desired applications are reported.

AB - This thesis investigated properties of organic-inorganic hybrids. Organic-inorganic hybrids are materials that consist of organic and inorganic components that are combined into a single compound. Organic and inorganic compounds generally have different properties: organic compounds have a flexible structure and are easy to make, while inorganic compounds are known for their excellent electronic and magnetic properties and resilience against high temperatures. Combining both components into a single hybrid compound gives rise to materials with properties that are associated with both components. Therefore, unique materials that are the best of both worlds can be created.While several properties of organic-inorganic hybrids have been reported, their origin is not always fully understood. The mechanisms behind the physical phenomena are sometimes yet to be found. It is commonly understood that the properties are directly related to the crystal structure, but there is still a lot to gain.The main goal of the research was to gain a better fundamental understanding of structure-property relations in organic-inorganic hybrids. In other words, how displacements in the crystal structure can change fundamental physical properties, including optical, electric and magnetic properties. In this work, both new and previously reported organic-inorganic hybrids are synthesized, their crystal structures are studied and fundamental physical properties are measured. The findings of this thesis add to the understanding of the chemistry, structures and physical properties of these hybrid materials. Furthermore, a few tools that are of use for direct tuning of certain physical properties of organic-inorganic hybrids for desired applications are reported.

M3 - Thesis fully internal (DIV)

SN - 978-94-034-0702-9

PB - Rijksuniversiteit Groningen

CY - [Groningen]

ER -

Properties of organic-inorganic hybrids: Chemistry, connectivity and confinement

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