Reorganization from Kinetically Stable Aggregation States to Thermodynamically Stable Nanotubes of BINOL-derived Amphiphiles in Water

Filippo Tosi; Marc C A Stuart; Hans Smit; Jiawen Chen; Ben L Feringa

doi:10.1021/acs.langmuir.9b01989

Reorganization from Kinetically Stable Aggregation States to Thermodynamically Stable Nanotubes of BINOL-derived Amphiphiles in Water

Filippo Tosi, Marc C A Stuart, Hans Smit, Jiawen Chen^*, Ben L Feringa

^*Corresponding author voor dit werk

Onderzoeksoutput: Article › Academic › peer review

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The synthesis and self-assembly behavior of newly designed BINOL-based amphiphiles is presented. With minor structural modifications, the aggregation of these amphiphiles could be successfully tuned to form different types of assemblies in water, ranging from vesicles to cubic structures. Simple sonication induced rearrangement of different kinetically stable aggregates into thermodynamically stable self-assembled nanotubes as observed by Cryo-TEM.

Originele taal-2	English
Pagina's (van-tot)	11821-11828
Aantal pagina's	8
Tijdschrift	Langmuir
Volume	35
Nummer van het tijdschrift	36
Vroegere onlinedatum	19-aug.-2019
DOI's	https://doi.org/10.1021/acs.langmuir.9b01989
Status	Published - 10-sep.-2019

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10.1021/acs.langmuir.9b01989Licentie: CC BY-NC-ND

Reorganization from Kinetically Stable Aggregation States toThermodynamically Stable Nanotubes of BINOL-DerivedAmphiphiles in WaterFinal publisher's version, 2,01 MBLicentie: CC BY-NC-ND

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title = "Reorganization from Kinetically Stable Aggregation States to Thermodynamically Stable Nanotubes of BINOL-derived Amphiphiles in Water",

abstract = "The synthesis and self-assembly behavior of newly designed BINOL-based amphiphiles is presented. With minor structural modifications, the aggregation of these amphiphiles could be successfully tuned to form different types of assemblies in water, ranging from vesicles to cubic structures. Simple sonication induced rearrangement of different kinetically stable aggregates into thermodynamically stable self-assembled nanotubes as observed by Cryo-TEM.",

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year = "2019",

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T1 - Reorganization from Kinetically Stable Aggregation States to Thermodynamically Stable Nanotubes of BINOL-derived Amphiphiles in Water

AU - Tosi, Filippo

AU - Stuart, Marc C A

AU - Smit, Hans

AU - Chen, Jiawen

AU - Feringa, Ben L

PY - 2019/9/10

Y1 - 2019/9/10

N2 - The synthesis and self-assembly behavior of newly designed BINOL-based amphiphiles is presented. With minor structural modifications, the aggregation of these amphiphiles could be successfully tuned to form different types of assemblies in water, ranging from vesicles to cubic structures. Simple sonication induced rearrangement of different kinetically stable aggregates into thermodynamically stable self-assembled nanotubes as observed by Cryo-TEM.

AB - The synthesis and self-assembly behavior of newly designed BINOL-based amphiphiles is presented. With minor structural modifications, the aggregation of these amphiphiles could be successfully tuned to form different types of assemblies in water, ranging from vesicles to cubic structures. Simple sonication induced rearrangement of different kinetically stable aggregates into thermodynamically stable self-assembled nanotubes as observed by Cryo-TEM.

KW - LEWIS-ACID

KW - BIOLOGICAL-PROPERTIES

KW - MICELLAR CATALYSIS

KW - ALDOL REACTIONS

KW - VESICLES

KW - MEMBRANE

KW - CHEMISTRY

KW - PHASES

KW - GUIDE

U2 - 10.1021/acs.langmuir.9b01989

DO - 10.1021/acs.langmuir.9b01989

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JO - Langmuir

JF - Langmuir

IS - 36

ER -

Reorganization from Kinetically Stable Aggregation States to Thermodynamically Stable Nanotubes of BINOL-derived Amphiphiles in Water

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