Secondary phases in AlxCoCrFeNi high-entropy alloys: An in-situ TEM heating study and thermodynamic appraisal

J. C. Rao, H. Y. Diao, V. Ocelík, D. Vainchtein, C. Zhang, C. C. Kuo, Z. Tang, W. Guo, J. D. Poplawsky, Y. Zhou, P. K. Liaw*, J. Th M. De Hosson

*Bijbehorende auteur voor dit werk

    OnderzoeksoutputAcademicpeer review

    219 Citaten (Scopus)
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    Secondary phases, either introduced by alloying or heat treatment, are commonly present in most high-entropy alloys (HEAs). Understanding the formation of secondary phases at high temperatures, and their effect on mechanical properties, is a critical issue that is undertaken in the present study, using the AlxCoCrFeNi (x = 0.3, 0.5, and 0.7) as a model alloy. The in-situ transmission-electron-microscopy (TEM) heating observation, an atom-probe-tomography (APT) study for the reference starting materials (Al0.3 and Al0.5 alloys), and thermodynamic calculations for all three alloys, are performed to investigate (1) the aluminum effect on the secondary-phase fractions, (2) the annealing-twinning formation in the face-centered-cubic (FCC) matrix, (3) the strengthening effect of the secondary ordered body-centered-cubic (B2) phase, and (4) the nucleation path of the σ secondary phase thoroughly. The present work will substantially optimize the alloy design of HEAs and facilitate applications of HEAs to a wide temperature range.

    Originele taal-2English
    Pagina's (van-tot)206-220
    Aantal pagina's15
    TijdschriftActa Materialia
    StatusPublished - 1-jun-2017

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