Samenvatting
The novel supramolecular silver(I) compound with formula [Ag-6(TST)(2)(bipy)(6)(H2O)(2)](n) center dot 3nH(2)O (1) based on assembly of Ag(I) and mixed ligand bipy/TST3-, bipy = 2,2'-bipyridine, H3TST = 2,4,6-tris(4-sulfophenylamino)-1,3,5-triazine, has been prepared by hydrothermal method. In the solid-state structure of 1, two-dimensional layered polymeric structures extended with subunits [Ag-6(TST)(2)(bipy)(6)(H2O)(2)] interact each other in the form of pi-pi attractions between bipy, forming a three-dimensional supramolecular architecture. Compound 1 represents a Ag-containing polymeric compound possessing room-temperature luminescence. (c) 2007 Elsevier B.V. All rights reserved.
Originele taal-2 | English |
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Pagina's (van-tot) | 1289-1293 |
Aantal pagina's | 5 |
Tijdschrift | Inorganic Chemistry Communications |
Volume | 10 |
Nummer van het tijdschrift | 11 |
DOI's | |
Status | Published - nov.-2007 |
Datasets
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CCDC 636258: Experimental Crystal Structure Determination
Yu, Y. (Contributor), Wei, Y. (Contributor), Braam, R. (Contributor) & Wu, K. (Contributor), University of Groningen, 8-feb.-2007
DOI: 10.5517/ccpc2gk
Dataset