@article{3c2691baa9cd47029a4d1e82e269adca,
title = "Site-Selective Electrochemical Oxidation of Glycosides",
abstract = "Quinuclidine-mediated electrochemical oxidation of glycopyranosides provides C3-ketosaccharides with high selectivity and good yields. The method is a versatile alternative to Pd-catalyzed or photochemical oxidation and is complementary to the 2,2,6,6-tetramethylpiperidine 1-oxyl (TEMPO)-mediated C6-selective oxidation. Contrary to the electrochemical oxidation of methylene and methine groups, the reaction proceeds without oxygen.",
keywords = "glycosides, site-selective, electrosynthesis, oxidation, metal-free conditions",
author = "Marios Kidonakis and Augustin Villotet and Witte, {Martin D.} and Beil, {Sebastian B.} and Minnaard, {Adriaan J.}",
note = "Funding Information: The Advanced Research Center Chemical Building Blocks Consortium (ARC CBBC) is acknowledged for funding. Funding Information: This work is supported by the ARC CBBC, which is co-founded and co-financed by the Netherlands Organization for Scientific Research (NWO) and the Netherlands Ministry of Economic Affairs. We acknowledge Prof. S.R. Waldvogel for kindly providing electrochemical equipment. Publisher Copyright: {\textcopyright} 2023 The Authors. Published by American Chemical Society.",
year = "2023",
month = feb,
day = "17",
doi = "10.1021/acscatal.2c06318",
language = "English",
volume = "13",
pages = "2335--2340",
journal = "ACS Catalysis",
issn = "2155-5435",
publisher = "AMER CHEMICAL SOC",
number = "4",
}