Stabilisation of mu-peroxido-bridged Fe(III) intermediates with non-symmetric bidentate N-donor ligands

Jozsef S. Pap, Apparao Draksharapu, Michel Giorgi, Wesley R. Browne*, Jozsef Kaizer, Gabor Speier

*Bijbehorende auteur voor dit werk

OnderzoeksoutputAcademicpeer review

13 Citaten (Scopus)

Samenvatting

The spectroscopic characterisation of the (mu-1,2-peroxido) diiron(III) species formed transiently upon reaction of [Fe(II)(NN)(3)](2+) complexes with H2O2 by UV/vis absorption and resonance Raman spectroscopy is reported. The intermediacy of such species in the disproportionation of H2O2 is demonstrated.

Originele taal-2English
Pagina's (van-tot)1326-1329
Aantal pagina's4
TijdschriftChemical Communications
Volume50
Nummer van het tijdschrift11
DOI's
StatusPublished - 2014

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