Structure of (1α,3β,5α)-5-chloro-1,3-di­phenyl-5-bis­(tri­methylsilyl)methyl-1λ6,3λ6,2,4,6,5λ5-di­thiatri­aza­phosphorine 1,3-dioxide

A. Meetsma; J. K. Herrema; J. C. van de Grampel

doi:10.1107/S010827018700862X

Structure of (1α,3β,5α)-5-chloro-1,3-diphenyl-5-bis(trimethylsilyl)methyl-1λ6,3λ6,2,4,6,5λ5-dithiatriazaphosphorine 1,3-dioxide

A. Meetsma
, J. K. Herrema
, J. C. van de Grampel

Onderzoeksoutput › Academic › peer review

1 Citaat (Scopus)

Samenvatting

C19H29CIN302PS2Si~, Mr=518"17, monoclinic, P21/n, a= 10.751 (3), b= 22.48 (1), c= 10.942 (3)A, fl=108.58(2) ° , V=2507(2)A 3, Z= 4, D x= 1.373gcm -3, MoK~, 2=0.71073A, g= 4.9 cm -x, F(000) = 1088, T= 130 K, R = 0.069 for 2831 observed reflections with I> 2.5a(I). The inorganic ring skeleton has an envelope conformation. The S-N and P-N bond lengths (mean values) are 1.562 (6) and 1.590 (8)A, respectively. One of the phenyl rings exhibits a disordered behaviour.

Originele taal-2	English
Pagina's (van-tot)	181-183
Aantal pagina's	3
Tijdschrift	Acta Crystallographica Section C: Crystal Structure Communications
Volume	44
DOI's	https://doi.org/10.1107/S010827018700862X
Status	Published - 15-jan-1988

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Structure of (1 a,3fl,5a)-5-Chloro- 1,3-diphenyl-5-bis(trimethylsilyl)
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@article{1daa61ae6fdd470cbad17769ae07eb18,

title = "Structure of (1α,3β,5α)-5-chloro-1,3-diphenyl-5-bis(trimethylsilyl)methyl-1λ6,3λ6,2,4,6,5λ5-dithiatriazaphosphorine 1,3-dioxide",

abstract = "C19H29CIN302PS2Si\textasciitilde{}, Mr=518{"}17, monoclinic, P21/n, a= 10.751 (3), b= 22.48 (1), c= 10.942 (3)A, fl=108.58(2) ° , V=2507(2)A 3, Z= 4, D x= 1.373gcm -3, MoK\textasciitilde{}, 2=0.71073A, g= 4.9 cm -x, F(000) = 1088, T= 130 K, R = 0.069 for 2831 observed reflections with I> 2.5a(I). The inorganic ring skeleton has an envelope conformation. The S-N and P-N bond lengths (mean values) are 1.562 (6) and 1.590 (8)A, respectively. One of the phenyl rings exhibits a disordered behaviour. ",

author = "A. Meetsma and Herrema, \{J. K.\} and \{van de Grampel\}, \{J. C.\}",

year = "1988",

month = jan,

day = "15",

doi = "10.1107/S010827018700862X",

language = "English",

volume = "44",

pages = "181--183",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

}

TY - JOUR

T1 - Structure of (1α,3β,5α)-5-chloro-1,3-diphenyl-5-bis(trimethylsilyl)methyl-1λ6,3λ6,2,4,6,5λ5-dithiatriazaphosphorine 1,3-dioxide

AU - Meetsma, A.

AU - Herrema, J. K.

AU - van de Grampel, J. C.

PY - 1988/1/15

Y1 - 1988/1/15

N2 - C19H29CIN302PS2Si~, Mr=518"17, monoclinic, P21/n, a= 10.751 (3), b= 22.48 (1), c= 10.942 (3)A, fl=108.58(2) ° , V=2507(2)A 3, Z= 4, D x= 1.373gcm -3, MoK~, 2=0.71073A, g= 4.9 cm -x, F(000) = 1088, T= 130 K, R = 0.069 for 2831 observed reflections with I> 2.5a(I). The inorganic ring skeleton has an envelope conformation. The S-N and P-N bond lengths (mean values) are 1.562 (6) and 1.590 (8)A, respectively. One of the phenyl rings exhibits a disordered behaviour.

AB - C19H29CIN302PS2Si~, Mr=518"17, monoclinic, P21/n, a= 10.751 (3), b= 22.48 (1), c= 10.942 (3)A, fl=108.58(2) ° , V=2507(2)A 3, Z= 4, D x= 1.373gcm -3, MoK~, 2=0.71073A, g= 4.9 cm -x, F(000) = 1088, T= 130 K, R = 0.069 for 2831 observed reflections with I> 2.5a(I). The inorganic ring skeleton has an envelope conformation. The S-N and P-N bond lengths (mean values) are 1.562 (6) and 1.590 (8)A, respectively. One of the phenyl rings exhibits a disordered behaviour.

U2 - 10.1107/S010827018700862X

DO - 10.1107/S010827018700862X

M3 - Comment/Letter to the editor

SN - 0108-2701

VL - 44

SP - 181

EP - 183

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

ER -