Subpromille Measurements and Calculations of CO (3-0) Overtone Line Intensities

Katarzyna Bielska, Aleksandra A. Kyuberis, Zachary D. Reed, Gang Li, Agata Cygan, Roman Ciuryło, Erin M. Adkins, Lorenzo Lodi, Nikolay F. Zobov, Volker Ebert, Daniel Lisak, Joseph T. Hodges, Jonathan Tennyson*, Oleg L. Polyansky

*Corresponding author voor dit werk

OnderzoeksoutputAcademicpeer review

20 Citaten (Scopus)
61 Downloads (Pure)

Samenvatting

Intensities of lines in the near-infrared second overtone band (3-0) of C12O16 are measured and calculated to an unprecedented degree of precision and accuracy. Agreement between theory and experiment to better than 1‰ is demonstrated by results from two laboratories involving two independent absorption- and dispersion-based cavity-enhanced techniques. Similarly, independent Fourier transform spectroscopy measurements of stronger lines in this band yield mutual agreement and consistency with theory at the 1‰ level. This set of highly accurate intensities can provide an intrinsic reference for reducing biases in future measurements of spectroscopic peak areas.

Originele taal-2English
Artikelnummer043002
Aantal pagina's6
TijdschriftPhysical Review Letters
Volume129
Nummer van het tijdschrift4
DOI's
StatusPublished - 22-jul.-2022

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